FactSage FTsalt salt database

List of systems and phases

 

 

 

The following tables summarize the contents of the FactSage FTsalt molten salt database in terms of the systems and phases it includes. The listings assist in phase selection for particular calculations by providing:

 

-    A LIST OF all binary, QUASIBINARY, PSEUDOBINARY, ternary and RECIPROCAL TERNARY SYSTEMS WHICH HAVE BEEN ASSESSED

 

-    A LIST OF ALL ASSESSED phases IN EACH OF THE SYSTEMS

 

-    ASSiSTANCE WITH PHASE SELECTION

 

Phase diagrams have been calculated for all the binary systems and for some quasibinary and pseudobinary sections using the assessed parameters contained in the database. The diagram for a particular binary, quasibinary or pseudobinary system can be viewed by clicking on the system as listed in Tables 1 and 2 below. The diagrams contain the names of the stable phases in each system. Tables 3 and 4 refer to the ternary systems and reciprocal ternary systems (those containing two cations and two anions) respectively, and provide guidance in phase selection for calculations in higher-order systems.

 

The phases listed for the binary and higher-order systems may be solution phases or stoichiometric compound phases (ST). 

 

When searching for a particular system in the present four tables, use alphabetical order of:

      - the cations for a common anion system (Tables 1 and 3)

      - the anions for a common cation system (Table 1)

      -  the compounds (end-members) for a quasibinary or pseudobinary system (Table 2)

      -  the cations for a reciprocal ternary system …, ... // Cl, F (Table 4)

 

 

TABLE 1 : List of phases for BINARY systems :

 

Complete assessments based on all experimental data from the literature are available for most systems listed below. For a few systems, owing to the lack of relevant data, some estimations have been made based on chemically similar systems or available data for higher-order systems (these systems are clearly identified below).

 

Click on the system name to view the stable phase diagram calculated with the stored parameters.

 

Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.

 

(I-option) – the phase displays a miscibility gap; selection with the I-option is required.

 

AlCl3-based systems : AlCl3 is a highly volatile species. For all AlCl3-based systems, all gaseous species from the FactPS compound database have been considered for the calculations, and calculations have been made at 1 bar total pressure.  (The notation “(GAS)” is used). In several of these systems the calculated figures contain phase boundaries shown as dotted lines. These are condensed phase boundaries calculated for high pressures when the gas phase does not appear.

 

NiCl2-based systems : NiCl2 is a volatile species and, for all NiCl2-based systems, the calculated 1 bar total pressure isobar (obtained using all gaseous species from the FactPS compound database) is superimposed to the calculated phase diagram.

 

The calculated phase diagrams are presented in 2 different sections:

- Common ANION systems (Anion = Br, CO3, Cl, F, I, NO3, OH or SO4)

- Common CATION systems (Cation = Ca, Cs, K, Li, Mg, Na or Rb)

 

Common ANION systems :

 

Anion = Br

 

CsBr-KBr

ESalt-liquid                                 CsBr-[KBr-RbBr](ss)                AlkBr(ss)

 

CsBr-LiBr

ESalt-liquid                                 CsBr(ST)                                      LiCsBr2(ST)                                LiBr(ST)

 

CsBr-NaBr

ESalt-liquid                                 CsBr(ST)                                      NaBr(ST)                           

 

CsBr-RbBr

ESalt-liquid                                 CsBr-[KBr-RbBr](ss)                AlkBr(ss)

 

KBr-LiBr

ESalt-liquid                                 KBr(ST)                                        LiBr(ST)

 

KBr-NaBr

ESalt-liquid                                 AlkBr(ss) (I-option)

 

KBr-RbBr

ESalt-liquid                                 AlkBr(ss)

 

LiBr-NaBr

ESalt-liquid                                 AlkBr(ss) (I-option)

 

LiBr-RbBr

ESalt-liquid                                 LiBr(ST)                                        LiRbBr2(ST)                               RbBr(ST)

 

NaBr-RbBr

ESalt-liquid                                 NaBr(ST)                                     RbBr(ST)

 

 

Anion = CO3

 

K2CO3-Li2CO3

FSalt-liquid                                  K2CO3(ST2)                               K2CO3(ST)                                  KLi(CO3)(ST)

Li2CO3(ST3)                               Li2CO3(ST2)                               Li2CO3(ST)

 

K2CO3-Na2CO3

FSalt-liquid                                  [Li],Na,K//SO4,CO3(ss)           K,Na//CO3,SO4(ss)

Na2CO3-[K2CO3](LT)             Na2CO3-[K2CO3](HT)

 

Li2CO3-Na2CO3

FSalt-liquid                                  [Li],Na,K//SO4,CO3(ss)           Li2CO3(ST3)                               Li2CO3(ST2)

Li2CO3(ST)                                 Na2CO3(ST2)                            Na2CO3(ST)

 

 

Anion = Cl

 

AlCl3-CaCl2

CSalt-liquid (I-option)          AlCl3(ST)                            CaAlCl5(ST)                        CaCl2(ST)

(GAS)

 

AlCl3-CoCl2

CSalt-liquid (I-option)          AlCl3(ST)                            CoAl2Cl8(ST)                      CoCl2(ST)

(GAS)

(Note : estimated from experimental data for the NaCl-AlCl3-CoCl2 ternary system)

 

AlCl3-FeCl2

CSalt-liquid (I-option)          AlCl3(ST)                                                                      FeAl2Cl8(ST)                        FeCl2(ST)

(GAS)

 

AlCl3-KCl

CSalt-liquid (I-option)          AlCl3(ST)                            KAlCl4(ST)                           KCl(ST)

(GAS)

 

AlCl3-LiCl

CSalt-liquid (I-option)          AlCl3(ST)                           LiAlCl4(ST)                          LiCl(ST)

(GAS)

 

AlCl3-MgCl2

CSalt-liquid(I-option)           AlCl3(ST)                            MgAl2Cl8(ST)                      MgCl2(ST)

(GAS)

 

AlCl3-MnCl2

CSalt-liquid (I-option)          AlCl3(ST)                            MnAl2Cl8(ST)                     MnCl2(ST)

(GAS)

 

AlCl3-NaCl

CSalt-liquid (I-option)          AlCl3(ST)                            NaAlCl4(ST)                                        NaCl(ST)

(GAS)

 

AlCl3-NiCl2

CSalt-liquid (I-option)          AlCl3(ST)                            NiAl2Cl8(ST)                        NiCl2(ST)

(GAS)

(Note : estimated from chemically similar systems like AlCl3-MgCl2)

 

AlCl3-ZnCl2

ISalt-liquid (I-option)            AlCl3(ST)                            ZnCl2(ST)                            (GAS)

 

BaCl2-CaCl2

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   CaBaCl4(ST)                                           CaCl2(ST)

 

BaCl2-CsCl

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   CsBaCl3(ST)                                           Cs2BaCl4(ST)                            CsCl(ST2)                                    CsCl(ST)

 

BaCl2-KCl

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   K2BaCl4(ST)                                           KCl(ST)

 

BaCl2-LiCl

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   LiCl(ST)

 

BaCl2-MgCl2

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   MgBa2Cl6(ST)                                        MgCl2(ST)

 

BaCl2-NaCl

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   NaCl(ST)

 

BaCl2-RbCl

DSalt-liquid                                 BaCl2(ST2)                                 BaCl2(ST)                                   Rb2BaCl4(ST)                                        RbCl(ST)

 

BaCl2-SrCl2

DSalt-liquid                                 (Sr,Ba,[Ca])Cl2(HT)                  (Ba,[Sr])Cl2(LT)                         (Ca,Sr,[Ba,Mg])Cl2(ss)                 

 

CaCl2-CoCl2

BSalt-liquid                                 CaCl2(ST)                                   CoCl2(ST)

 

CaCl2-CsCl

DSalt-liquid                                 CaCl2(ST)                                   CsCaCl3(ST)                              CsCl(ST2)                                              CsCl(ST)

 

CaCl2-FeCl2

BSalt-liquid                                 CaCl2(ST)                                   FeCl2(ST)

 

CaCl2-FeCl3

BSalt-liquid                                 CaCl2(ST)                                   CaFeCl5(ST)                              FeCl3(ST)

(Note : estimated from experimental data for the CaCl2-MgCl2-MnCl2-FeCl3 quaternary system)

 

CaCl2-KCl

ASalt-liquid                                 CaCl2(ST)                                   KCl(ST)                                         KCaCl3(ST)

 

CaCl2-LiCl

ASalt-liquid                                 CaCl2(ST)                                   LiCl(ST)

 

CaCl2-MgCl2

ASalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss)            MgCl2(ST)

 

CaCl2-MnCl2

BSalt-liquid                                 CaCl2(ST)                                   MnCl2(ST)

 

CaCl2-NaCl

ASalt-liquid                                 AlkCl-ss_rocksalt                      CaCl2(ST)    

 

CaCl2-NiCl2

BSalt-liquid                                 CaCl2(ST)                                   NiCl2(ST)              

 

CaCl2-PbCl2

HSalt-liquid                                 CaCl2(ST)                                   PbCl2(ST)

 

CaCl2-RbCl

DSalt-liquid                                 CaCl2(ST)                                   RbCaCl3(ST)                             RbCl(ST)

 

CaCl2-SrCl2

DSalt-liquid                                 (Sr,Ba,[Ca])Cl2(HT)                  (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)         

 

CaCl2-ZnCl2

ISalt-liquid                                   CaCl2(ST)                                   ZnCl2(ST)

 

CeCl3-CsCl

GSalt-liquid                                 CeCl3(ST)                                   CsCe2Cl7(ST)                            Cs3CeCl6(ST)                             CsCl(ST2)                                                                CsCl(ST)

 

CeCl3-KCl

GSalt-liquid                                 CeCl3(ST)                                   K3Ce5Cl18(ST)                          K2CeCl5(ST)                                      K3CeCl6(ST)                              KCl(ST)

 

CeCl3-LiCl

GSalt-liquid                                 CeCl3(ST)                                   LiCl(ST)

 

CeCl3-NaCl

GSalt-liquid                                 CeCl3(ST)                                   Na3Ce5Cl18(ST)                      NaCl(ST)

 

CeCl3-RbCl

GSalt-liquid                                 CeCl3(ST)                                   RbCe2Cl7(ST)                           Rb2CeCl5(ST)                                  Rb3CeCl6(ST)                           RbCl(ST)

 

CoCl2-FeCl2

BSalt-liquid                                 MCl2_SOLID

 

CoCl2-FeCl3

BSalt-liquid                                 CoCl2(ST)                                   CoFe2Cl8(ST)                            FeCl3(ST)

(Note : estimated from experimental data for the MnCl2-FeCl3 system)

 

CoCl2-KCl

BSalt-liquid                                 CoCl2(ST)                                   KCoCl3(ST)                                 K2CoCl4(ST)

KCl(ST)

 

CoCl2-LiCl

BSalt-liquid                                 BAlkCl-ss_rocksalt                   CoCl2(ST)                                   LiCoCl3(ST)                                        Li2CoCl4(ST)                              Li4CoCl6(ST)                                                 

 

CoCl2-MgCl2

BSalt-liquid                                 MCl2_SOLID

 

CoCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID (I-option)

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only and is not

based on experimental data.)

 

CoCl2-NaCl

BSalt-liquid                                 CoCl2(ST)                                   Na2CoCl4(ST)                           NaCl(ST)

 

CoCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)                                         

 

CsCl-KCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (I-option)

(Note : calculated phase boundaries below 470 oC are predicted only, and are not based

on experimental data.)

 

CsCl-LaCl3

GSalt-liquid                                 CsCl(ST2)                                    CsCl(ST)                                      Cs3LaCl6(ST)                                        CsLa2Cl7(ST)                            LaCl3(ST)

 

CsCl-LiCl

DSalt-liquid                                 CsCl(ST2)                                    CsCl(ST)                     LiCs2Cl3(ST)                                          LiCl(ST)

 

CsCl-MgCl2

DSalt-liquid                                 CsCl(ST2)                                    CsCl(ST)                     Cs3MgCl5(ST)

Cs2MgCl4(ST)                           CsMgCl3(ST)                             CsMg3Cl7(ST)                           MgCl2(ST)

 

CsCl-NaCl

DSalt-liquid                                 CsCl(ST2)                                    CsCl(ST)                                      NaCl(ST)

 

CsCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt                   CsCl(ST)                 

 

CsCl-SrCl2

DSalt-liquid                                 CsCl(ST2)                                    CsCl(ST)                                      CsSrCl3(ST)                                        SrCl2(ST2)                                  SrCl2(ST)

 

FeCl2-FeCl3

BSalt-liquid                                 FeCl2(ST)                                    FeCl3(ST)                                    (GAS)

 

FeCl2-KCl

BSalt-liquid                                 FeCl2(ST)                                    K2FeCl4(ST)                               KFeCl3(ST)
KCl(ST)

 

FeCl2-LiCl

BSalt-liquid                                 BAlkCl-ss_rocksalt                   FeCl2(ST)                                    Li2FeCl4(ST)

Li6FeCl8(ST)

 

FeCl2-MgCl2

BSalt-liquid                                 MCl2_SOLID

 

FeCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID

 

FeCl2-NaCl

BSalt-liquid                                 FeCl2(ST)                                    Na2FeCl4(ST)                           NaCl(ST)

 

FeCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)                 

 

FeCl3-LiCl

BSalt-liquid                                 FeCl3(ST)                                    LiFeCl4(ST)                                LiCl(ST)

 

FeCl3-MgCl2

BSalt-liquid                                 FeCl3(ST)                                    MgFe2Cl8(ST)                           MgCl2(ST)

(Note : estimated from experimental data for the FeCl3-MnCl2 system)

 

FeCl3-MnCl2

BSalt-liquid                                 FeCl3(ST)                                    MnFe2Cl8(ST)                           MnCl2(ST)

 

FeCl3-NiCl2

BSalt-liquid                        FeCl3(ST)                                    NiFe2Cl8(ST)                             NiCl2(ST)

(GAS)

(Note : estimated from experimental data for the FeCl3-MnCl2 system)

 

KCl-LaCl3

GSalt-liquid                                 LaCl3(ST)                                    K3La5Cl18(ST)                          K2LaCl5(ST)

KCl(ST)

 

KCl-LiCl

ASalt-liquid                                 KCl(ST)                                         LiCl(ST)

 

KCl-MgCl2

ASalt-liquid                                 KCl(ST)                                         K3Mg2Cl7(ST)                           K2MgCl4(ST)

KMgCl3(ST)                                MgCl2(ST)

 

KCl-MnCl2

BSalt-liquid                                 KCl(ST)                                         K4MnCl6(ST)             K3Mn2Cl7(ST)

KMnCl3(ST)                                MnCl2(ST)

 

KCl-NaCl                                          

ASalt-liquid                                 AAlkCl-ss_rocksalt (I-option)                       

 

KCl-NiCl2

BSalt-liquid                         KCl(ST)                                         KNiCl3(ST)                                  NiCl2(ST)

 

KCl-PbCl2

HSalt-liquid                                 KCl(ST)                                         K2PbCl4(ST)                              KPb2Cl5(ST)                                   PbCl2(ST)

                           

KCl-RbCl

DSalt-liquid                                 AlkCl-ss_rocksalt

 

KCl-SrCl2

DSalt-liquid                                 KCl(ST)                                         K2SrCl4(ST)                                KSr2Cl5(ST)                                          SrCl2(ST2)                                  SrCl2(ST)

 

KCl-ZnCl2

ISalt-liquid                           KCl(ST)                                         K2ZnCl4(ST)                               K5Zn4Cl13(ST)

KZn2Cl5(ST)                               ZnCl2(ST)

 

LaCl3-LiCl

GSalt-liquid                                 LaCl3(ST)                                    LiCl(ST)

 

LaCl3-NaCl

GSalt-liquid                                 LaCl3(ST)                                    Na3La5Cl18(ST)                       NaCl(ST)

 

LaCl3-RbCl

GSalt-liquid                                 LaCl3(ST)                                    RbLa2Cl7(ST)                            Rb2LaCl5(ST)                                         Rb3LaCl6(ST)                            RbCl(ST)

 

LiCl-MgCl2

ASalt-liquid                                 AAlkCl-ss_rocksalt                   MCl2_SOLID

 

LiCl-MnCl2

BSalt-liquid                                 BAlkCl-ss_rocksalt                   Li2MnCl4(ST)                             MnCl2(ST)  

 

LiCl-NaCl

ASalt-liquid                                 AAlkCl-ss_rocksalt (I-option)                                         

 

LiCl-NiCl2

BSalt-liquid                                                                   BAlkCl-ss_rocksalt                   Li6NiCl8(ST)                                                        Li2NiCl4(ST)                                   NiCl2(ST)                

 

LiCl-RbCl

DSalt-liquid                                 LiCl(ST)                                        LiRbCl2(ST)                                RbCl(ST)             

 

LiCl-SrCl2

DSalt-liquid                                 LiCl(ST)                                        SrCl2(ST2)                                  SrCl2(ST)

 

MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID

 

MgCl2-NaCl

ASalt-liquid                                 MgCl2(ST)                                   NaMgCl3(ST)                             Na2MgCl4(ST)

NaCl(ST)

 

MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)          

(Note : estimated from experimental data for the NaCl-KCl-MgCl2-NiCl2 quaternary system)

 

MgCl2-RbCl

DSalt-liquid                                 MgCl2(ST)                                   RbMgCl3(ST)                             Rb2MgCl4(ST)                                   RbCl(ST)

 

MgCl2-SrCl2

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss)            MgCl2(ST)                                   SrCl2(ST2)    

 

MgCl2-ZnCl2

ISalt-liquid                                   MgCl2(ST)                                   ZnCl2(ST)    

 

MnCl2-NaCl

BSalt-liquid                                 MnCl2(ST)                                   NaMn4Cl9(ST)                           Na2Mn3Cl8(ST)                           Na9Mn11Cl31(ST)                    Na2MnCl4(ST)                           Na6MnCl8(ST)                           NaCl(ST)

 

MnCl2-NiCl2

BSalt-liquid                        MCl2_SOLID (I-option)                                                        

 

NaCl-NiCl2

BSalt-liquid                                        NaCl(ST)                                                         NiCl2(ST)                       

 

NaCl-PbCl2

HSalt-liquid                                 NaCl(ST)                                     PbCl2(ST)

 

NaCl-RbCl

DSalt-liquid                                 AlkCl-ss_rocksalt (I-option)

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

NaCl-SrCl2

DSalt-liquid                                 NaCl(ST)                                     SrCl2(ST2)                                  SrCl2(ST)

 

NaCl-ZnCl2

ISalt-liquid                                   NaCl(ST)                                     Na2ZnCl4(ST)                            ZnCl2(ST)

 

RbCl-SrCl2

DSalt-liquid                                 RbCl(ST)                                     RbSrCl3(ST)                               RbSr2Cl5(ST)                              SrCl2(ST2)                                                                                 SrCl2(ST)

 

 

Anion = F

 

CaF2-KF

ASalt-liquid                                 CaF2(ST2)                                  CaF2(ST)                                     KCaF3(ST)         

KF(ST)

 

CaF2-LiF

ASalt-liquid                                 CaF2(ST2)                                  CaF2(ST)                                     LiF(ST)

 

CaF2-MgF2

ASalt-liquid                                 CaF2(ST2)                                  CaF2(ST)                                     MgF2(ST)

 

CaF2-NaF

ASalt-liquid                                 CaF2(ST2)                                  CaF2(ST)                                     NaF(ST)

 

CsF-KF

ESalt-liquid                                 AlkF(ssA)                                     KF(ST)

 

CsF-LiF

ESalt-liquid                                 CsF(ST)                                       LiCsF2(ST)                                  LiF(ST)

 

CsF-NaF

ESalt-liquid                                 CsF(ST)                                       NaF(ST)

 

CsF-RbF

ESalt-liquid                                 AlkF(ssA)

 

KF-LiF

ASalt-liquid                                 KF(ST)                                          LiF(ST)

 

KF-MgF2

ASalt-liquid                                 KF(ST)                                          K2MgF4(ST)                               KMgF3(ST)

MgF2(ST)

 

KF-NaF

ASalt-liquid                                 AlkF(ssA)                                     NaF(ST)

 

KF-RbF

ESalt-liquid                                 AlkF(ssA)

 

LiF-MgF2

ASalt-liquid                                 LiF-[MgF2](ss)                           MgF2-[LiF](ss)

 

LiF-NaF

ASalt-liquid                                 LiF(ST)                                         NaF-[LiF](ss)  

 

LiF-PuF3

JSalt-liquid                                  LiF(ST)                                         PuF3(ST)                                    

 

LiF-PuF4

JSalt-liquid                                  LiF(ST)                                         Li4PuF8(ST)                               Li7Pu6F31(ST)

LiPu4F17(ST)                             PuF4(ST)

 

LiF-RbF

ESalt-liquid                                 LiF(ST)                                         LiRbF2(ST)                                 RbF(ST)

 

LiF-ThF4

JSalt-liquid                                  LiF(ST)                                         Li3ThF7(ST)                               Li7Th6F31(ST)

LiTh2F9(ST)                               LiTh4F17(ST)                             ThF4(ST)

 

LiF-UF4

JSalt-liquid                                  LiF(ST)                                         Li4UF8(ST)                Li7U6F31(ST)

LiU4F17(ST)                               UF4(ST)

 

MgF2-NaF

ASalt-liquid                                 MgF2(ST)                                    NaMgF3(ST)                              NaF(ST)

 

NaF-RbF

ESalt-liquid                                 NaF(ST)                                       RbF(ST)                                             

 

PuF3-ThF4

JSalt-liquid                                  PuF3(ST)                                     ThF4(ST)                   

 

 

Anion = I

 

CsI-KI 

ESalt-liquid                                 CsI-[KI-RbI](ss)                          AlkI(ss)

 

CsI-LiI

ESalt-liquid                                 CsI(ST)                                         LiI(ST)

 

CsI-NaI

ESalt-liquid                                 CsI(ST)                                         NaI(ST)

 

CsI-RbI

ESalt-liquid                                 CsI-[KI-RbI](ss)                          AlkI(ss)

 

KI-LiI

ESalt-liquid                                 KI(ST)                                            LiI(ST)

 

KI-NaI

ESalt-liquid                                 AlkI(ss) (I-option)

 

KI-RbI

ESalt-liquid                                 AlkI(ss)

                                                                                                               

LiI-NaI

ESalt-liquid                                 AlkI(ss)

 

LiI-RbI

ESalt-liquid                                 LiI(ST)                                           LiRbI2(ST)                                   RbI(ST)

 

NaI-RbI

ESalt-liquid                                 AlkI(ss) (I-option)                   

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

 

Anion = NO3

 

CsNO3-KNO3

ESalt-liquid                                 Rb,Cs,[K]//NO3(ss)                  Na,K,[Rb,Cs]//NO3(ss)           CsNO3-[KNO3](ss)                 KNO3(ST)

 

CsNO3-LiNO3

ESalt-liquid                                 CsNO3(ST2)                               CsNO3(ST)                                 CsLi(NO3)2(ST)                   LiNO3(ST)

 

CsNO3-NaNO3

ESalt-liquid                                 CsNO3(ST2)                               CsNO3(ST)                                 NaNO3(ST2)

NaNO3(ST)

 

CsNO3-RbNO3                         

ESalt-liquid                                 Rb,Cs,[K]//NO3(ss)                  CsNO3(ST)                                 RbNO3(ST3)

RbNO3(ST2)                              RbNO3(ST)

(Note : calculated phase boundaries below 290 oC are predicted only, and are not based

on experimental data.)

 

KNO3-LiNO3

ESalt-liquid                                 KNO3(ST2)                                 KNO3(ST)                                    LiNO3(ST)

 

KNO3-NaNO3

ESalt-liquid                                 Na,K,[Rb,Cs]//NO3(ss)           KNO3-[NaNO3](lt)                     NaNO3(ST)

 

KNO3-RbNO3

ESalt-liquid                                 Na,K,[Rb,Cs]//NO3(ss)           Rb,Cs,[K]//NO3(ss)                  RbNO3(ST3)

RbNO3(ST2)                              RbNO3(ST)                                KNO3(ST)

(Note : calculated phase boundaries below 285 oC are predicted only, and are not based

on experimental data.)

 

LiNO3-NaNO3

ESalt-liquid                                 LiNO3(ST)                                   NaNO3(ST2)                              NaNO3(ST)

 

LiNO3-RbNO3

ESalt-liquid                                 LiNO3(ST)                                   RbNO3(ST4)                              RbNO3(ST3)

RbNO3(ST2)                              RbNO3(ST)                                LiRb(NO3)2(ST)

 

NaNO3-RbNO3

ESalt-liquid                                 NaNO3(ST2)                              NaNO3(ST)                                NaRb3(NO3)4(ST)              RbNO3(ST4)                                                                               RbNO3(ST3)                              RbNO3(ST2)                              RbNO3(ST)

 

 

Anion = OH

 

CsOH-KOH

DSalt-liquid                                 CsOH(ST2)                                 CsOH(ST)                                   KOH(ST2)              KOH(ST)

 

CsOH-LiOH

DSalt-liquid                                 CsOH(ST)                                   CsOH(ST2)                                 CsLi5(OH)6(ST)

LiOH(ST)

 

CsOH-NaOH

DSalt-liquid                                 CsOH(ST2)                                 CsOH(ST)                                   NaOH(ST2)                NaOH(ST)

 

CsOH-RbOH

DSalt-liquid                                 K,Rb,Cs,[Na]//OH(HT)            CsOH(ST)                                   RbOH(ST)

 

KOH-LiOH

ASalt-liquid                                 KOH(ST2)                                    KOH(ST)                                      Li2K(OH)3(ST)

LiOH(ST)

 

KOH-NaOH              

ASalt-liquid                                 K,Rb,Cs,[Na]//OH(HT)            KOH-RbOH-[NaOH](LT)        NaOH(ST2)

NaOH(ST)

 

KOH-RbOH

DSalt-liquid                                 K,Rb,Cs,[Na]//OH(HT)            KOH-RbOH-[NaOH](LT)  

 

LiOH-NaOH

ASalt-liquid                                 NaOH-[LiOH](ss)                      LiOH(ST)                                     LiNa(OH)2(ST)

NaOH(ST)                 

 

LiOH-RbOH

DSalt-liquid                                 LiOH(ST)                                     Li2Rb(OH)3(ST)                        RbOH(ST2)

RbOH(ST)

 

NaOH-RbOH

DSalt-liquid                                 NaOH(ST)                                   NaOH(ST2)                                RbOH(ST)         RbOH(ST2)

 

 

Anion = SO4

 

K2SO4-Li2SO4

FSalt-liquid                                  [Li],Na,K//SO4,CO3(ss)           Li,Na,K//SO4,CO3(ss)              K2SO4(ST)                      KLi(SO4)(ST3)                                                                           KLi(SO4)(ST2)                            KLi(SO4)(ST)                              Li2SO4(ST)

 

K2SO4-Na2SO4

FSalt-liquid                         [Li],Na,K//SO4,CO3(ss)        K,Na//SO4,CO3(ss)             K3Na(SO4)2

Na2SO4-[K2SO4](ss)           Na2SO4(ST3)

 

Li2SO4-Na2SO4

FSalt-liquid                                  LiNaSO4                                      [Li],Na,K//SO4,CO3(ss)           Li,Na,K//SO4,CO3(ss)                  Li2SO4(ST)                                 Na2SO4(ST3)                            Na2SO4(ST)                              LiNaSO4(ST)

 

 

Common CATION systems :

 

Cation = Ca

 

CaCl2-CaF2

ASalt-liquid                                 CaCl2(ST)                                   CaFCl(ST)                                   CaF2(ST2)             CaF2(ST)

 

CaCl2-CaO

ASalt-liquid                                 CaCl2(ST)                                   CaO(ST)                                      Ca5OCl8(ST2)

Ca5OCl8(ST)                     

 

 

Cation = Cs

 

CsBr-CsCl

ESalt-liquid                                 Cs-Halides(ss)                          CsCl-[CsBr-CsI](ss)                  CsCl(ST)

(Note : calculated phase boundaries below 610 oC are predicted only, and are not based

on experimental data.)

 

CsBr-CsF

ESalt-liquid                                 CsBr(ST)                                      CsF(ST)

 

CsBr-CsI

ESalt-liquid                                 Cs-Halides(ss) (I-option)

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

CsBr-CsNO3

ESalt-liquid                                 CsNO3-CsBr(ss) (I-option)                                                           CsNO3(ST)

(Note : the calculated subsolidus is predicted only and is not based on experimental data.)

 

CsCl-CsF

ESalt-liquid                                 CsCl(ST2)                                    CsCl(ST)                    CsF(ST)

 

CsCl-CsI

ESalt-liquid                                 CsCl-[CsBr-CsI](ss)                  Cs-Halides(ss)         CsCl(ST)

 

CsCl-CsNO3

ESalt-liquid                                 CsCl-[CsNO3](ss)                     CsNO3-[CsCl](ss)                     CsCl(ST)

CsNO3(ST)

 

CsF-CsI

ESalt-liquid                                 CsF(ST)                                       CsI(ST)

 

CsF-CsNO3

ESalt-liquid                                 CsF(ST)                                       CsNO3(ST2)                               CsNO3(ST)

 

CsNO3-CsOH

ESalt-liquid                                 CsNO3-[CsOH](HT)                 CsNO3-[CsOH](LT)                  CsOH-[CsNO3](ss)         CsOH(ST)

 

 

Cation = K

 

KBr-KCl

ESalt-liquid                                 K-Halides(ssA)

 

KBr-KF

ESalt-liquid                                 KBr(ST)                                        KF(ST)

 

KBr-KI

ESalt-liquid                                 K-Halides(ssA) (I-option)

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

KBr-KNO3

ESalt-liquid                                 KNO3-[KBr](ss)                          KBr(ST)                                        KNO3(ST)

 

KBr-KOH

ESalt-liquid                                 KOH-[KBr](ss)                            KBr(ST)                                        KOH(ST)                      

 

K2CO3-KCl

FSalt-liquid                                  KCl(ST)                                         K2CO3(ST2)                               K2CO3(ST)

 

K2CO3-KF

FSalt-liquid                                  K2CO3(ST2)                               K2CO3(ST)                                  K3F(CO3)(ST)              KF(ST)

 

K2CO3-KNO3

FSalt-liquid                                  K2CO3(ST2)                               K2CO3(ST)                                  KNO3(ST2)

KNO3(ST)

 

K2CO3-KOH

FSalt-liquid                                  K2CO3(ST2)                               K2CO3(ST)                                  KOH(ST2)

KOH(ST)

 

K2CO3-K2SO4

FSalt-liquid                                  [Li],Na,K//SO4,CO3(ss)           K,Na//CO3,SO4(ss)                 

K,Na//SO4,CO3(ss)                 

 

KCl-KF

ASalt-liquid                                 KCl(ST)                                         KF(ST)

 

KCl-KI

ESalt-liquid                                 K-Halides(ssA) (I-option)                  

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only, and is not

based on experimental data.)

 

KCl-KNO3

ESalt-liquid                                 KCl(ST)                                         K2ClNO3(ST)                             KNO3(ST2)

KNO3(ST)

 

KCl-KOH

ASalt-liquid                                 KCl-KOH(ss) (I-option)         KOH(ST)                                     

 

KCl-K2SO4

FSalt-liquid                                  KCl(ST)                                         K2SO4(ST2)                               K2SO4(ST)

 

KF-KI

ESalt-liquid                                 KF(ST)                                          KI(ST)

 

KF-KNO3

ESalt-liquid                                 KF(ST)                                          KNO3(ST2)                                 KNO3(ST)

 

KF-KOH

ASalt-liquid                                 KF-KOH(ss) (I-option)       KOH(ST)

 

KF-K2SO4

FSalt-liquid                                  KF(ST)                                          K3F(SO4)(ST)                            K2SO4(ST2)

K2SO4(ST)

 

KI-KNO3

ESalt-liquid                                 KI(ST)                                            KNO3-[KI](ss)                             KNO3(ST)

 

KI-KOH

ESalt-liquid                                 KI(ST)                                            KOH(ST2)                                    KOH(ST)

 

KNO3-KOH

ESalt-liquid                                 KNO3(ST2)                                 KNO3(ST)                                    K2(OH)(NO3)(ST)

KOH(ST2)                                    KOH(ST)                           

 

KNO3-K2SO4

FSalt-liquid                                  KNO3(ST2)                                 KNO3(ST)                                    K2SO4(ST2)

K2SO4(ST)

 

KOH-K2SO4

FSalt-liquid                                  KOH(ST2)                                    KOH(ST)                                      K2SO4(ST2)

K2SO4(ST)

 

 

Cation = Li

 

LiBr-LiCl

ESalt-liquid                                 Li-Halides(ss)(I-option)

(Note : The calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

LiBr-LiNO3

ESalt-liquid                                 LiBr(ST)                                        LiNO3(ST)

 

LiBr-LiOH

ESalt-liquid                                 LiBr(ST)                                        Li2OHBr(ST)                               Li4(OH)3Br(ST)

LiOH(ST)

 

LiBr-LiF

ESalt-liquid                                 LiBr(ST)                                        LiF(ST)

 

LiBr-LiI

ESalt-liquid                                 Li-Halides(ss) )(I-option)   

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

Li2CO3-LiCl

FSalt-liquid                                  LiCl(ST)                                        Li2CO3(ST3)                               Li2CO3(ST2)

Li2CO3(ST)

 

Li2CO3-LiF

FSalt-liquid                                  Li2CO3(ST3)                               Li2CO3(ST2)                               Li2CO3(ST)

LiF(ST)

 

Li2CO3-LiNO3

FSalt-liquid                                  Li2CO3(ST3)                               Li2CO3(ST2)                               Li2CO3(ST)

LiNO3(ST)

 

Li2CO3-LiOH

FSalt-liquid                                  Li2CO3(ST3)                               Li2CO3(ST2)                               Li2CO3(ST)

LiOH(ST)

 

Li2CO3-Li2SO4

FSalt-liquid                                  Li,Na,K//SO4,CO3(ss)              Li2CO3(ST3)                               Li2CO3(ST2)                                         Li2CO3(ST)                                 Li2SO4(ST)

 

LiCl-LiF

ASalt-liquid                                 LiCl(ST)                                        LiF(ST)

 

LiCl-LiI

ESalt-liquid                                 LiCl(ST)                                        LiI(ST)

 

LiCl-LiNO3

ESalt-liquid                                 LiCl(ST)                                        LiNO3(ST)

 

LiCl-LiOH

ASalt-liquid                                 LiCl(ST)                                        LiOH(ST)                                     Li2OHCl(ST)

 

LiCl-Li2SO4

FSalt-liquid                                  LiCl(ST)                                        Li2SO4(ST2)                               Li2SO4(ST)

 

LiF-LiI                       

ESalt-liquid                                 LiF(ST)                                         LiI(ST)

 

LiF-LiNO3

ESalt-liquid                                 LiF(ST)                                         LiNO3(ST)

 

LiF-LiOH

ASalt-liquid                                 LiF(ST)                                         LiOH(ST)                    

 

LiF-Li2SO4

FSalt-liquid                                  LiF(ST)                                         Li2SO4(ST2)                               Li2SO4(ST)

                                       

LiI-LiOH

ESalt-liquid                                 LiI(ST)                                           Li2OHI(ST)                                  Li5(OH)4I(ST)

LiOH(ST)

 

LiNO3-LiOH

ESalt-liquid                                 LiNO3(ST)                                   Li2OHNO3(ST)                          LiOH(ST)

 

LiNO3-Li2SO4

FSalt-liquid                                  LiNO3(ST)                                   Li2SO4(ST2)                               Li2SO4(ST)

 

LiOH-Li2SO4

FSalt-liquid                                  LiOH(ST)                                     Li2SO4(ST2)                               Li2SO4(ST)

 

 

Cation = Mg

 

MgCl2-MgF2

ASalt-liquid                                 MgCl2(ST)                                   MgF2(ST)

 

MgCl2-MgO

ASalt-liquid                                 MgCl2(ST)                                   MgO(ST)

 

MgF2-MgO

ASalt-liquid                                 MgF2(ST)                                    MgO(ST)

 

 

Cation = Na

 

NaBr-NaCl

ESalt-liquid                                 Na-Halides(ssA)

 

NaBr-NaF

ESalt-liquid                                 NaBr(ST)                                     NaF(ST)

 

NaBr-NaI

ESalt-liquid                                 Na-Halides(ssA)

 

NaBr-NaNO3

ESalt-liquid                                 NaBr(ST)                                     NaNO3(ST2)                              NaNO3(ST)

 

NaBr-NaOH

ESalt-liquid                                 NaBr(ST)                                     NaOH(ST2)                                NaOH(ST)

 

Na2CO3-NaCl

FSalt-liquid                                  NaCl(ST)                                     Na2CO3(ST3)                            Na2CO3(ST2)

Na2CO3(ST)

 

Na2CO3-NaF

FSalt-liquid                                  Na2CO3(ST3)                            Na2CO3(ST2)                            Na2CO3(ST)

NaF(ST)

 

Na2CO3-NaNO3

FSalt-liquid                                  Na2CO3(ST3)                            Na2CO3(ST2)                            Na2CO3(ST)
NaNO3(ST2)                              NaNO3(ST)

 

Na2CO3-NaOH

FSalt-liquid                                  Na2CO3(ST3)                            Na2CO3(ST2)                            Na2CO3(ST)

NaOH(ST2)                                NaOH(ST)

 

Na2CO3-Na2SO4

FSalt-liquid                                  [Li],Na,K//SO4,CO3(ss)           Na2CO3(ST2)                            Na2CO3(ST)      Na2SO4(ST3)                                                        Na2SO4(ST)

 

NaCl-NaF

ASalt-liquid                                 NaCl(ST)                                     NaF(ST)

 

NaCl-NaI

ESalt-liquid                                 Na-Halides(ssA)                       Na-Halides(ssB)

 

NaCl-NaNO3

ESalt-liquid                                 NaCl(ST)                                     NaNO3(ST2)                              NaNO3(ST)

 

NaCl-NaOH

ASalt-liquid                                 NaCl-[NaOH](ss)                      NaOH-[NaCl](ss)                      NaOH(ST)

 

NaCl-Na2SO4

FSalt-liquid                                  NaCl(ST)                                     Na2SO4(ST3)                            Na2SO4(ST2)

Na2SO4(ST)

 

NaF-NaI

ESalt-liquid                                 NaF(ST)                                      NaI(ST)

 

NaF-NaNO3

ESalt-liquid                                 NaF(ST)                                       NaNO3(ST2)                              NaNO3(ST)

 

NaF-NaOH

ASalt-liquid                                 NaF-NaOH(ss) (I-option)   NaOH(ST)

 

NaF-Na2SO4

FSalt-liquid                                  NaF(ST)                                       Na3F(SO4)(ST)                         Na2SO4(ST3)

Na2SO4(ST2)                            Na2SO4(ST)

 

NaI-NaNO3

ESalt-liquid                                 NaI(ST)                                        NaNO3-[NaI](ss)                       NaNO3(ST)

 

NaI-NaOH

ESalt-liquid                                 NaI(ST)                                        Na5OHI4(ST)                             NaOH(ST2)                                      NaOH(ST)

 

NaNO3-NaOH

ESalt-liquid                                 NaNO3(ST2)                              NaNO3(ST)                                Na2OHNO3(ST)                         Na3(OH)2(NO3)(ST)                NaOH(ST2)                                NaOH(ST)

 

NaNO3-Na2SO4

FSalt-liquid                                  NaNO3(ST2)                              NaNO3(ST)                                Na2SO4(ST3)

Na2SO4(ST2)                            Na2SO4(ST)

 

NaOH-Na2SO4

FSalt-liquid                                  NaOH(ST2)                                NaOH(ST)                                   Na3(OH)(SO4)(ST)

Na2SO4(ST3)                            Na2SO4(ST2)                            Na2SO4(ST)

 

 

Cation = Rb

 

RbBr-RbCl

ESalt-liquid                                 Rb-Halides(ss)

 

RbBr-RbF

ESalt-liquid                                 RbBr(ST)                                     RbF(ST)

 

RbBr-RbI

ESalt-liquid                                 Rb-Halides(ss) (I-option)

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

RbBr-RbNO3

ESalt-liquid                                 RbNO3-RbBr(ss)                      RbNO3(ST3)                              RbNO3(ST2)

RbNO3(ST)

(Note : calculated phase boundaries below 300 oC are predicted only, and are not based

on experimental data.)

 

RbCl-RbF

ESalt-liquid                                 RbCl(ST)                                     RbF(ST)

 

RbCl-RbI

ESalt-liquid                                 Rb-Halides(ss) (I-option)

(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,

and is not based on experimental data.)

 

RbCl-RbOH

DSalt-liquid                                 RbCl-[RbOH](ss)                      RbOH-[RbCl](ss)                      RbOH(ST)

 

RbF-RbI

ESalt-liquid                                 RbF(ST)                                      RbI(ST)

 

RbNO3-RbOH

ESalt-liquid                                 RbNO3(ST4)                              RbNO3(ST3)                              RbNO3(ST2)

RbNO3(ST)                                Rb2OHNO3(ST)                       RbOH(ST2)                                RbOH(ST)

 

 

TABLE 2 : List of phases for QUASIBINARY

and/or PSEUDOBINARY sections :

 

Complete assessments based on all experimental data from the literature are available for the sections listed below.  That is, these are the sections for which experimental data are available and have been used in the optimizations.

 

Click on the system name to view the stable phase diagram calculated with the stored parameters.

 

Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.

 

(I-option) – the phase displays a miscibility gap; selection with the I-option is required.

 

AlCl3-based systems : AlCl3 is a highly volatile species. For all AlCl3-based systems, all gaseous species from the FactPS compound database have been considered for the calculations, and calculations have been made at 1 bar total pressure.  (The notation “(GAS)” is used). In some of these systems the calculated figures contain phase boundaries shown as dotted lines. These are condensed phase boundaries calculated for high pressures when the gas phase does not appear.

 

 

CaCl2-MgF2

ASalt-liquid               (Ca,Sr,[Ba,Mg])Cl2(ss)                              MgF2(ST)                                    CaFCl(ST)

 

CaCl2-NaAlCl4

CSalt-liquid (I-option)            CaCl2(ST)                                   NaAlCl4(ST)              (GAS)                          

 

CaF2-KCaCl3

ASalt-liquid                                 CAMX3-Perovskite                   CaF2(ST2)                  CaF2(ST)                 

KCl(ST)                                         CaFCl(ST)

(Note : The system has been optimized only in the composition range XKCaCl3 > 0.4)

 

KAlCl4-NaAlCl4

CSalt-liquid (I-option)            KAlCl4(ST)                                  NaAlCl4(ST)

 

KAlCl4-NaCl

CSalt-liquid(I-option)             AAlkCl-ss_rocksalt              KAlCl4(ST)                          NaAlCl4(ST)

 

KCl-LiF

ASalt-liquid                                 KCl(ST)                                         LiF(ST)                                         KF(ST)

LiCl(ST)

 

KCl-NaAlCl4

CSalt-liquid(I-option)             AAlkCl-ss_rocksalt(I-option)                                          KAlCl4(ST)

NaAlCl4(ST)

 

KFeCl3-NaCl

BSalt-liquid                                 BAlkCl-ss_rocksalt              FeCl2(ST)                                    KFeCl3(ST)                  

 

KMgCl3-LiCl

ASalt-liquid                                 AAMX3-Perovskite              AAlk2MX4                           AAlkCl-ss_rocksalt     K3Mg2Cl7(ST)                                          LiKMgCl4(ST)

 

KMgCl3-NaCl

ASalt-liquid                                 AAMX3-Perovskite              AAlk2MX4                           AAlkCl-ss_rocksalt    

K3Mg2Cl7(ST)

 

KMnCl3-NaCl

BSalt-liquid                                 BAlkCl-ss_rocksalt                   KMnCl3(ST)                                Na6MnCl8(ST)

 

LiAlCl4-NaAlCl4

CSalt-liquid (I-option)            LiAlCl4(ST)                                  NaAlCl4(ST)

 

LiF-NaCl

ASalt-liquid                         AAlkCl-ss_rocksalt              LiF(ST)                                         NaF-[LiF](ss)

 

LiTh2F9-LiU2F9

JSalt-liquid                                  (Th,U,Pu)F4(ss)                         Li(Th,U,Pu)4F17(ss)(I-option)

Li(Th,U,Pu)2F9(ss)(I-option)                                         Li7(Th,U,Pu)6F31(ss)(I-option)

Li3(Th,U,Pu)F7(ss)(I-option)                                         LiF(ST)                                        ThF4(ST)

UF3(ST)                                       UF4(ST)                                       Li4UF8(ST)

 

LiTh4F17-LiU4F17

JSalt-liquid                                  (Th,U,Pu)F4(ss)                         Li(Th,U,Pu)4F17(ss)(I-option)

Li(Th,U,Pu)2F9(ss)(I-option)                                         Li7(Th,U,Pu)6F31(ss)(I-option)

Li3(Th,U,Pu)F7(ss)(I-option)                                         LiF(ST)                                        ThF4(ST)

UF3(ST)                                       UF4(ST)                                       Li4UF8(ST)

 

Li3ThF7-Li3UF7

JSalt-liquid                                  (Th,U,Pu)F4(ss)                         Li(Th,U,Pu)4F17(ss)(I-option)

Li(Th,U,Pu)2F9(ss)(I-option)                                         Li7(Th,U,Pu)6F31(ss)(I-option)

Li3(Th,U,Pu)F7(ss)(I-option)                                         LiF(ST)                                        ThF4(ST)

UF3(ST)                                       UF4(ST)                                       Li4UF8(ST)

 

Li7Th6F31-Li7U6F31

JSalt-liquid                                  (Th,U,Pu)F4(ss)                         Li(Th,U,Pu)4F17(ss)(I-option)

Li(Th,U,Pu)2F9(ss)(I-option)                                         Li7(Th,U,Pu)6F31(ss)(I-option)

Li3(Th,U,Pu)F7(ss)(I-option)                                         LiF(ST)                                        ThF4(ST)

UF3(ST)                                       UF4(ST)                                       Li4UF8(ST)

 

 

TABLE 3 : List of phases for common-ion TERNARY systems with Cl or F:

 

Only the MAIN ternary systems are presented below. These are the common ANION systems with anion = Cl or F.

 

Ternary phase diagrams may be calculated using the phases listed below for each system. The following code of colours is used:

- For all ternary systems in purple, complete assessments based on all experimental data from the literature are available. Ternary parameters were added for the liquid and/or other phases (solid solutions) if needed.

- For all ternary systems in blue, no experimental data could be found in the literature. Consequently, the thermodynamic properties of the liquid (and solid solutions if they exist) are simply estimated from the optimized parameters of the binary subsystems using proper interpolation methods.

 

Beware - if some ternary phases are unknown, incorrect phase equilibria may be calculated. 

 

Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.

 

(I-option) ―  the phase displays a 2-phase immiscibility; selection with the I-option is required.

 

(J-option) ― the phase may display a 3-phase immiscibility; selection with the J-option is required.

 

Note: AlCl3 and NiCl2 are volatile.  Under certain conditions, the total gas pressure may be greater than 1 bar.  In this case, the gas phase should also be selected using all gases from the FactPS compound database.

 

Anion = Cl

 

AlCl3-CaCl2-CoCl2

CSalt-liquid (J-option)        AlCl3(ST)                                     CaCl2(ST)                                   CaAlCl5(ST)           CoCl2(ST)                                                                       CoAl2Cl8(ST)

 

AlCl3-CaCl2-FeCl2

CSalt-liquid (J-option)        AlCl3(ST)                                     CaCl2(ST)                                   CaAlCl5(ST)

FeCl2(ST)                                    FeAl2Cl8(ST)

 

AlCl3-CaCl2-FeCl3

CSalt-liquid (J-option)        AlCl3(ST)                                     CaCl2(ST)                                   CaAlCl5(ST)              FeCl3(ST)                                                         CaFeCl5(ST)               

 

AlCl3-CaCl2-KCl

CSalt-liquid (J-option)        KCl(ST)                                      AlCl3(ST)                                     KAlCl4(ST)          CaCl2(ST)                                                                                  CaAlCl5(ST)                               KCaCl3(ST)

 

AlCl3-CaCl2-LiCl

CSalt-liquid (J-option)        LiCl(ST)                                        AlCl3(ST)                                     LiAlCl4(ST)                       CaCl2(ST)                                                                                 CaAlCl5(ST)

 

AlCl3-CaCl2-MgCl2

CSalt-liquid (J-option)        (Ca,Sr,[Ba,Mg])Cl2(ss)            MgCl2(ST)                                   AlCl3(ST)                MgAl2Cl8(ST)                                                                    CaAlCl5(ST)

 

AlCl3-CaCl2-MnCl2

CSalt-liquid (J-option)       AlCl3(ST)                                     CaCl2(ST)                                   CaAlCl5(ST)             MnCl2(ST)                                                                   MnAl2Cl8(ST)

 

AlCl3-CaCl2-NaCl

CSalt-liquid (J-option)       AAlkCl-ss_rocksalt (J-option)                                       AlCl3(ST)            NaAlCl4(ST)                                                                        CaCl2(ST)                                   CaAlCl5(ST)

 

AlCl3-CaCl2-NiCl2

CSalt-liquid (J-option)        AlCl3(ST)                                     CaCl2(ST)                                   CaAlCl5(ST)               NiCl2(ST)                                                                 NiAl2Cl8(ST)

 

AlCl3-CaCl2-ZnCl2

ISalt-liquid (J-option)         AlCl3(ST)                                     CaCl2(ST)                                   CaAlCl5(ST)             ZnCl2(ST)

 

AlCl3-CoCl2-FeCl2

CSalt-liquid (J-option)        MCl2_SOLID                               AlCl3(ST)                                     FeAl2Cl8(ST)                         CoAl2Cl8(ST)                                                               CoFe2Cl8(ST)

 

AlCl3-CoCl2-FeCl3

CSalt-liquid (J-option)        AlCl3(ST)                                     FeCl3(ST)                                    CoCl2(ST)           CoAl2Cl8(ST)                                                         CoFe2Cl8(ST)          

 

AlCl3-CoCl2-KCl

CSalt-liquid (J-option)        KCl(ST)                               AlCl3(ST)                                     KAlCl4(ST)                      CoCl2(ST)                                                               CoAl2Cl8(ST)                             KCoCl3(ST)                                 K2CoCl4(ST)

 

AlCl3-CoCl2-LiCl

CSalt-liquid (J-option)        BAlkCl-ss_rocksalt (J-option)                                       AlCl3(ST)                                                           LiAlCl4(ST)                                  CoCl2(ST)                                   LiCoCl3(ST)                                Li2CoCl4(ST)                   Li4CoCl6(ST)                                                                            CoAl2Cl8(ST)                   

 

AlCl3-CoCl2-MgCl2

CSalt-liquid (J-option)       MCl2_SOLID                               AlCl3(ST)                                     MgAl2Cl8(ST)             CoAl2Cl8(ST)

 

AlCl3-CoCl2-MnCl2

CSalt-liquid (J-option)                                                  MCl2_SOLID                               AlCl3(ST)                                                               MnAl2Cl8(ST)              CoAl2Cl8(ST)

 

AlCl3-CoCl2-NaCl

CSalt-liquid (J-option)        NaCl(ST)                                   AlCl3(ST)                                     NaAlCl4(ST) CoCl2(ST)                                                                 Na2CoCl4(ST)                           CoAl2Cl8(ST)      

 

AlCl3-CoCl2-NiCl2

CSalt-liquid (J-option)       MCl2_SOLID(I-option)        AlCl3(ST)                                     CoAl2Cl8(ST)              NiAl2Cl8(ST)

 

AlCl3-FeCl2-FeCl3

CSalt-liquid (J-option)       AlCl3(ST)                                     FeCl2(ST)                                    FeCl3(ST)            FeAl2Cl8(ST)

 

AlCl3-FeCl2-KCl

CSalt-liquid (J-option)        KCl(ST)                               AlCl3(ST)                                     KAlCl4(ST)         FeCl2(ST)                                                                    FeAl2Cl8(ST)                             KFeCl3(ST)                                 K2FeCl4(ST)

 

AlCl3-FeCl2-LiCl

CSalt-liquid (J-option)       BAlkCl-ss_rocksalt (J-option)                                       AlCl3(ST)                        LiAlCl4(ST)                                                                          FeCl2(ST)                                    Li2FeCl4(ST)                              Li6FeCl8(ST)                       FeAl2Cl8(ST)

 

AlCl3-FeCl2-MgCl2

CSalt-liquid (J-option)       MCl2_SOLID                               AlCl3(ST)                                     MgAl2Cl8(ST)   FeAl2Cl8(ST)

 

AlCl3-FeCl2-MnCl2

CSalt-liquid (J-option)       MCl2_SOLID                               AlCl3(ST)                                     MnAl2Cl8(ST)                        FeAl2Cl8(ST)

 

AlCl3-FeCl2-NaCl

CSalt-liquid (J-option)       NaCl(ST)                            AlCl3(ST)                                     NaAlCl4(ST)                       FeCl2(ST)                                                                    Na2FeCl4(ST)                           FeAl2Cl8(ST)

 

AlCl3-FeCl2-NiCl2

CSalt-liquid (J-option)       MCl2_SOLID(I-option)        AlCl3(ST)                                     FeAl2Cl8(ST)                          NiAl2Cl8(ST)

 

AlCl3-FeCl3-KCl

CSalt-liquid (J-option)                                                  AlCl3(ST)                                     KCl(ST)                                           KAlCl4(ST)                FeCl3(ST)                                    KFeCl4(ST)

 

AlCl3-FeCl3-LiCl

CSalt-liquid (J-option)       LiCl(ST)                                        AlCl3(ST)                                     LiAlCl4(ST)                 FeCl3(ST)                                                                   LiFeCl4(ST)                     

 

AlCl3-FeCl3-MgCl2

CSalt-liquid (J-option)       MgCl2(ST)                                   AlCl3(ST)                                     MgAl2Cl8(ST)                   FeCl3(ST)                                                                  MgFe2Cl8(ST)

 

AlCl3-FeCl3-MnCl2

CSalt-liquid (J-option)       AlCl3(ST)                                     MnCl2(ST)                                   MnAl2Cl8(ST)                 FeCl3(ST)                                                                  MnFe2Cl8(ST)

 

AlCl3-FeCl3-NaCl

CSalt-liquid (J-option)                                                  NaCl(ST)                                     AlCl3(ST)                                                                        NaAlCl4(ST)                 FeCl3(ST)                                                  NaFeCl4(ST)

 

AlCl3-FeCl3-NiCl2

CSalt-liquid (J-option)       AlCl3(ST)                                     FeCl3(ST)                                    NiCl2(ST)        NiAl2Cl8(ST)                                                                        NiFe2Cl8(ST)

 

AlCl3-KCl-LiCl

CSalt-liquid (J-option)        KCl(ST)                                         LiCl(ST)                              AlCl3(ST)            LiAlCl4(ST)                                                                   KAlCl4(ST)

 

AlCl3-KCl-MgCl2

CSalt-liquid (J-option)       KCl(ST)                               MgCl2(ST)                                   AlCl3(ST)

MgAl2Cl8(ST)                            KMgCl3(ST)                                K2MgCl4(ST)                              K3Mg2Cl7(ST)               KAlCl4(ST)

 

AlCl3-KCl-MnCl2

CSalt-liquid (J-option)       KCl(ST)                               AlCl3(ST)                                     KAlCl4(ST)        MnCl2(ST)                                                                 MnAl2Cl8(ST)                             KMnCl3(ST)                                K4MnCl6(ST)                K3Mn2Cl7(ST)

 

AlCl3-KCl-NaCl

CSalt-liquid (J-option)        AAlkCl-ss_rocksalt (J-option)                                              AlCl3(ST)             NaAlCl4(ST) KAlCl4(ST)

 

AlCl3-KCl-NiCl2

CSalt-liquid (J-option)       KCl(ST)                               AlCl3(ST)                                     KAlCl4(ST)   

NiCl2(ST)                                     NiAl2Cl8(ST)                              KNiCl3(ST)

 

AlCl3-KCl-ZnCl2

ISalt-liquid (J-option)         KCl(ST)                               AlCl3(ST)                                     KAlCl4(ST)                  

ZnCl2(ST)                                    K2ZnCl4(ST)                               K5Zn4Cl13(ST)                          KZn2Cl5(ST)

 

AlCl3-LiCl-MgCl2

CSalt-liquid (J-option)        MCl2_SOLID                               AAlkCl-ss_rocksalt (J-option)        

AlCl3(ST)                                     LiAlCl4(ST)                                  MgAl2Cl8(ST)      

 

AlCl3-LiCl-MnCl2

CSalt-liquid (J-option)        BAlkCl-ss_rocksalt (J-option)                                       AlCl3(ST)                 LiAlCl4(ST)                                                                 MnCl2(ST)                                   Li2MnCl4(ST)                             MnAl2Cl8(ST)

 

AlCl3-LiCl-NaCl

CSalt-liquid (J-option)       AAlkCl-ss_rocksalt (J-option)                                       AlCl3(ST)             LiAlCl4(ST)                                                                  NaAlCl4(ST)

 

AlCl3-LiCl-NiCl2

CSalt-liquid (J-option)                                                  BAlkCl-ss_rocksalt (J-option)                                        AlCl3(ST)            LiAlCl4(ST)                                  NiCl2(ST)                                     Li2NiCl4(ST)                               Li6NiCl8(ST)                          NiAl2Cl8(ST)

 

AlCl3-MgCl2-MnCl2

CSalt-liquid (J-option)        MCl2_SOLID                               AlCl3(ST)                                     MgAl2Cl8(ST)                           MnAl2Cl8(ST)

 

AlCl3-MgCl2-NaCl

CSalt-liquid (J-option)        NaCl(ST)                                  MgCl2(ST)                                   NaMgCl3(ST)          Na2MgCl4(ST)                                                               AlCl3(ST)                                     NaAlCl4(ST)                               MgAl2Cl8(ST)

 

AlCl3-MgCl2-NiCl2

CSalt-liquid (J-option)        MCl2_SOLID (I-option)         AlCl3(ST)                                     MgAl2Cl8(ST)             NiAl2Cl8(ST)

 

AlCl3-MgCl2-ZnCl2

ISalt-liquid (J-option)         MgCl2(ST)                                   AlCl3(ST)                                     MgAl2Cl8(ST)                           ZnCl2(ST)

 

AlCl3-MnCl2-NaCl

CSalt-liquid (J-option)        NaCl(ST)                            AlCl3(ST)                                     NaAlCl4(ST)      MnCl2(ST)                                                             Na2MnCl4(ST)                           Na6MnCl8(ST)                           Na2Mn3Cl8(ST)         NaMn4Cl9(ST)                                                                   Na9Mn11Cl31(ST)                    MnAl2Cl8(ST)

 

AlCl3-MnCl2-NiCl2

CSalt-liquid (J-option)       MCl2_SOLID (I-option)      AlCl3(ST)                                     MnAl2Cl8(ST)           NiAl2Cl8(ST)

 

AlCl3-NaCl-NiCl2

CSalt-liquid (J-option)        NaCl(ST)                            AlCl3(ST)                                     NaAlCl4(ST)          NiCl2(ST)                                                                  NiAl2Cl8(ST)

 

AlCl3-NaCl-ZnCl2

ISalt-liquid (J-option)         NaCl(ST)                                  AlCl3(ST)                                     NaAlCl4(ST)          ZnCl2(ST)                                                               Na2ZnCl4(ST)

 

BaCl2-CaCl2-CsCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)     (Sr,Ba,[Ca])Cl2(HT)                  BAlk2MX4(J-option)          BaCl2(ST)                                   CsCl(ST) 

CsCl(ST2)                                    CaBaCl4(ST)

 

BaCl2-CaCl2-KCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)   (Sr,Ba,[Ca])Cl2(HT)                  BAlk2MX4(J-option)          KCl(ST)                               BaCl2(ST)                    CaBaCl4(ST)

 

BaCl2-CaCl2-LiCl

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss)         (Sr,Ba,[Ca])Cl2(HT)                  LiCl(ST)                

BaCl2(ST)                                   CaBaCl4(ST)

 

BaCl2-CaCl2-MgCl2

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)                  MgCl2(ST)                            BaCl2(ST)                                                             MgBa2Cl6(ST)                           CaBaCl4(ST)

 

BaCl2-CaCl2-NaCl

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)                 

AAlkCl-ss_rocksalt (J-option)                                       BaCl2(ST)                                   CaBaCl4(ST)

 

BaCl2-CaCl2-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)                                    (Sr,Ba,[Ca])Cl2(HT)                  BAlk2MX4(J-option)         RbCl(ST)                           BaCl2(ST)                   CaBaCl4(ST)          

 

BaCl2-CaCl2-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                         (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                        (Sr,Ba,[Ca])Cl2(HT)                                                                CaBaCl4(ST)

 

BaCl2-CsCl-KCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)           

AAlkCl-ss_rocksalt (J-option)                                                CsCl(ST)                                      BaCl2(ST)             BaCl2(ST2)            

 

BaCl2-CsCl-LiCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)           

LiCl(ST)                              CsCl(ST)                                      CsCl(ST2)                                    LiCs2Cl3(ST)               

BaCl2(ST)                                   BaCl2(ST2)                  

 

BaCl2-CsCl-MgCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)                               MgCl2(ST)                                   CsCl(ST)                                      CsCl(ST2)                                    CsMg3Cl7(ST)            Cs3MgCl5(ST)                                                                 BaCl2(ST)                                   BaCl2(ST2)                                 MgBa2Cl6(ST)

 

BaCl2-CsCl-NaCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)           

CsCl(ST)                                      CsCl(ST2)                                    NaCl(ST)                                     BaCl2(ST)               BaCl2(ST2)                

 

BaCl2-CsCl-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)           

AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)                                      BaCl2(ST)

BaCl2(ST2)                               

 

BaCl2-CsCl-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                         BAMX3-Perovskite (J-option)            (Ca,Sr,[Ba,Mg])Cl2(ss)                                                        (Sr,Ba,[Ca])Cl2(HT)                  BAlk2MX4 (J-option)          CsCl(ST)                 CsCl(ST2)                           

 

BaCl2-KCl-LiCl

DSalt-liquid                                 BAlk2MX4 (J-option)           KCl(ST)                                       LiCl(ST)

BaCl2(ST)                                   BaCl2(ST2)                   

 

BaCl2-KCl-MgCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)         KCl(ST)                                          MgCl2(ST)                                   K3Mg2Cl7(ST)                        BaCl2(ST)             BaCl2(ST2)                                                                    MgBa2Cl6(ST)

 

BaCl2-KCl-NaCl

DSalt-liquid                                 BAlk2MX4 (J-option)         AAlkCl-ss_rocksalt (J-option)               

BaCl2(ST)                                   BaCl2(ST2)                     

 

BaCl2-KCl-RbCl

DSalt-liquid                                 BAlk2MX4 (J-option)                                                    AAlkCl-ss_rocksalt (J-option)                

BaCl2(ST)                           BaCl2(ST2)        

 

BaCl2-KCl-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                         (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)             AlkM2Cl5(I-option)                                        BAlk2MX4 (J-option)                                                    KCl(ST)                                          

 

BaCl2-LiCl-MgCl2

DSalt-liquid                                 MCl2_SOLID                               AAlkCl-ss_rocksalt (J-option)                                                  

BaCl2(ST)                                   BaCl2(ST2)                                 MgBa2Cl6(ST)

 

BaCl2-LiCl-NaCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       BaCl2(ST)             BaCl2(ST2)                                 

 

BaCl2-LiCl-RbCl

DSalt-liquid                                 BAlk2MX4 (J-option)           LiCl(ST)                                      RbCl(ST)

LiRbCl2(ST)                                BaCl2(ST)                                   BaCl2(ST2)                            

 

BaCl2-LiCl-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                         (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)

LiCl(ST)                                       

 

BaCl2-MgCl2-NaCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)           

NaCl(ST)                            MgCl2(ST)                                   BaCl2(ST)                                   BaCl2(ST2) MgBa2Cl6(ST)                     Na3Mg2BaCl9(ST)

 

BaCl2-MgCl2-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)       

RbCl(ST)                            MgCl2(ST)                                   BaCl2(ST)                                   BaCl2(ST2)         MgBa2Cl6(ST)

 

BaCl2-MgCl2-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                   (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)      

MgCl2(ST)                                   MgBa2Cl6(ST)

 

BaCl2-NaCl-RbCl

DSalt-liquid                                 BAlk2MX4 (J-option)          AAlkCl-ss_rocksalt (J-option)               

BaCl2(ST)                                   BaCl2(ST2)               

 

BaCl2-NaCl-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                         (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)        NaCl(ST)

 

BaCl2-RbCl-SrCl2

DSalt-liquid                                 (Ba,[Sr])Cl2(LT)                         BAMX3-Perovskite (J-option)                                         (Ca,Sr,[Ba,Mg])Cl2(ss)            (Sr,Ba,[Ca])Cl2(HT)                  AlkM2Cl5 (I-option)                BAlk2MX4 (J-option)

RbCl(ST)

 

CaCl2-CoCl2-FeCl2

BSalt-liquid                                 MCl2_SOLID                               CaCl2(ST)             

 

CaCl2-CoCl2-FeCl3

BSalt-liquid                                 CaCl2(ST)                                   FeCl3(ST)                                    CaFeCl5(ST)              CoCl2(ST)                                                                     CoFe2Cl8(ST)

 

CaCl2-CoCl2-KCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)       

KCl(ST)                               CaCl2(ST)                                   CoCl2(ST)                               

 

CaCl2-CoCl2-LiCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)       

BAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)                                   CoCl2(ST)

Li4CoCl6(ST)

 

CaCl2-CoCl2-MgCl2

BSalt-liquid                                 MCl2_SOLID                               (Ca,Sr,[Ba,Mg])Cl2(ss)       

 

CaCl2-CoCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                               CaCl2(ST)                   

 

CaCl2-CoCl2-NaCl

BSalt-liquid                                 AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)                   CaCl2(ST)            CoCl2(ST)          

 

CaCl2-CoCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)         CaCl2(ST)          

 

CaCl2-CsCl-KCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

AAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)                           CsCl(ST)

 

CaCl2-CsCl-LiCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       CaCl2(ST)                    CsCl(ST)                                          CsCl(ST2)                                    LiCl(ST)                                        LiCs2Cl3(ST)             

 

CaCl2-CsCl-MgCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)         

BAlk2MX4 (J-option)          MgCl2(ST)                                   CsCl(ST)                                      CsCl(ST2)

CsMg3Cl7(ST)                           Cs3MgCl5(ST)

 

CaCl2-CsCl-NaCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

AAlkCl-ss_rocksalt (J-option)                                                CaCl2(ST)                                   CsCl(ST) 

 

CaCl2-CsCl-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

AAlkCl-ss_rocksalt (J-option)                                                CaCl2(ST)                                   CsCl(ST)        

 

CaCl2-CsCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

(Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                                   (Sr,Ba,[Ca])Cl2(HT)                 

CsCl(ST)                                      CsCl(ST2)

 

CaCl2-FeCl2-FeCl3

BSalt-liquid                                 CaCl2(ST)                                   FeCl2(ST)                                    FeCl3(ST)              CaFeCl5(ST)

 

CaCl2-FeCl2-KCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)

KCl(ST)                                         CaCl2(ST)                                   FeCl2(ST)              

 

CaCl2-FeCl2-LiCl

BSalt-liquid                                 AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)               

CaCl2(ST)                                   FeCl2(ST)                           Li6FeCl8(ST)                             

 

CaCl2-FeCl2-MgCl2

BSalt-liquid                                 MCl2_SOLID                               (Ca,Sr,[Ba,Mg])Cl2(ss)             

 

CaCl2-FeCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                               CaCl2(ST)          

 

CaCl2-FeCl2-NaCl

BSalt-liquid                                 AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)                    CaCl2(ST)                                                                      FeCl2(ST)

 

CaCl2-FeCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)         CaCl2(ST)            

 

CaCl2-FeCl3-KCl

BSalt-liquid                                 KCl(ST)                               CaCl2(ST)                                   KCaCl3(ST)            FeCl3(ST)                                                                   KFeCl4(ST)                                 CaFeCl5(ST)

 

CaCl2-FeCl3-LiCl

BSalt-liquid                                 LiCl(ST)                                        CaCl2(ST)                                   FeCl3(ST)           LiFeCl4(ST)                                                                              CaFeCl5(ST)

 

CaCl2-FeCl3-MgCl2

BSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss)            MgCl2(ST)                                   FeCl3(ST)

MgFe2Cl8(ST)                           CaFeCl5(ST)

 

CaCl2-FeCl3-MnCl2

BSalt-liquid                                 CaCl2(ST)                                   MnCl2(ST)                                   FeCl3(ST)             CaFeCl5(ST)                                                                        MnFe2Cl8(ST)

 

CaCl2-FeCl3-NaCl

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)         FeCl3(ST)                                                                     NaFeCl4(ST)                              CaFeCl5(ST)

 

CaCl2-FeCl3-NiCl2

BSalt-liquid                                 CaCl2(ST)                                   FeCl3(ST)                                    CaFeCl5(ST)            NiCl2(ST)                                                                       NiFe2Cl8(ST)

 

CaCl2-KCl-LiCl

ASalt-liquid                                 AAMX3-Perovskite (J-option)                                       KCl(ST)

LiCl(ST)                              CaCl2(ST)  

 

CaCl2-KCl-MgCl2

ASalt-liquid                                 AAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)

AAlk2MX4 (J-option)          KCl(ST)                                         MgCl2(ST)                                   K3Mg2Cl7(ST)

      

CaCl2-KCl-MnCl2

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       KCl(ST)    

CaCl2(ST)                                   MnCl2(ST)                                   K4MnCl6(ST)                              K3Mn2Cl7(ST)

 

CaCl2-KCl-NaCl

ASalt-liquid                                 AAMX3-Perovskite (J-option)                                                

AAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)         

 

CaCl2-KCl-NiCl2

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                                KCl(ST)

CaCl2(ST)                                   NiCl2(ST)

 

CaCl2-KCl-PbCl2

HSalt-liquid                                 KCl(ST)                                         CaCl2(ST)                                   KCaCl3(ST)            PbCl2(ST)                                                                  K2PbCl4(ST)                              KPb2Cl5(ST)

 

CaCl2-KCl-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

AAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)           

 

CaCl2-KCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

(Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                                   (Sr,Ba,[Ca])Cl2(HT)                  BAlk2MX4 (J-option)       KCl(ST)                                          KSr2Cl5(ST)

 

CaCl2-KCl-ZnCl2

ISalt-liquid                                   KCl(ST)                                         CaCl2(ST)                                   KCaCl3(ST)            ZnCl2(ST)                                                                  K2ZnCl4(ST)                               K5Zn4Cl13(ST)                          KZn2Cl5(ST)

 

CaCl2-LiCl-MgCl2

ASalt-liquid                                 MCl2_SOLID                               (Ca,Sr,[Ba,Mg])Cl2(ss)                          

AAlkCl-ss_rocksalt (J-option)            

 

CaCl2-LiCl-MnCl2

BSalt-liquid                                 AAlk2MX4 (J-option)         BAlkCl-ss_rocksalt (J-option)           

CaCl2(ST)                                   MnCl2(ST)              

 

CaCl2-LiCl-NaCl

ASalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)       

 

CaCl2-LiCl-NiCl2

BSalt-liquid                                 AAlk2MX4 (J-option)           BAlkCl-ss_rocksalt (J-option)                                      

CaCl2(ST)                                   NiCl2(ST)                                     Li6NiCl8(ST)

 

CaCl2-LiCl-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       LiCl(ST)    

RbCl(ST)                                     CaCl2(ST)                                LiRbCl2(ST)              

 

CaCl2-LiCl-SrCl2

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                                   (Sr,Ba,[Ca])Cl2(HT)      

LiCl(ST)   

 

CaCl2-MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                               (Ca,Sr,[Ba,Mg])Cl2(ss)  

 

CaCl2-MgCl2-NaCl

ASalt-liquid                                 AAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)     AAlk2MX4(J-option)                                       AAlkCl-ss_rocksalt (J-option)                                                MgCl2(ST)                 

 

CaCl2-MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       (Ca,Sr,[Ba,Mg])Cl2(ss)        

 

CaCl2-MgCl2-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)        BAlk2MX4(J-option)                                    RbCl(ST)                            MgCl2(ST)                   

 

CaCl2-MgCl2-SrCl2

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                                   (Sr,Ba,[Ca])Cl2(HT)      MgCl2(ST)              

 

CaCl2-MgCl2-ZnCl2

ISalt-liquid                                   (Ca,Sr,[Ba,Mg])Cl2(ss)                                                   MgCl2(ST) 

ZnCl2(ST)            

 

CaCl2-MnCl2-NaCl

BSalt-liquid                                 AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)               

CaCl2(ST)                                   MnCl2(ST)                                   Na6MnCl8(ST)                           Na2Mn3Cl8(ST)               NaMn4Cl9(ST)                                                               Na9Mn11Cl31(ST)

 

CaCl2-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       CaCl2(ST)       

 

CaCl2-NaCl-NiCl2

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)       NiCl2(ST)     

 

CaCl2-NaCl-PbCl2

HSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                                   CaCl2(ST)               PbCl2(ST)    

 

CaCl2-NaCl-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

AAlkCl-ss_rocksalt (J-option)                                                   CaCl2(ST)    

 

CaCl2-NaCl-SrCl2

DSalt-liquid                                 (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                                   (Sr,Ba,[Ca])Cl2(HT)       AAlkCl-ss_rocksalt (J-option)             

 

CaCl2-NaCl-ZnCl2

ISalt-liquid                                   AAlkCl-ss_rocksalt (J-option)                                       CaCl2(ST)       ZnCl2(ST)                                                        Na2ZnCl4(ST)     

 

CaCl2-RbCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                      

(Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)                                   (Sr,Ba,[Ca])Cl2(HT)                 

RbCl(ST)                            RbSr2Cl5(ST)

 

CeCl3-CsCl-KCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST) 

CeCl3(ST)                                   K2CeCl5(ST)                              K3CeCl6(ST)                              K3Ce5Cl18(ST)           Cs3CeCl6(ST)                                                                         CsCe2Cl7(ST)

 

CeCl3-CsCl-LaCl3

GSalt-liquid                                 RareEarth-Chloride(ss)          CsCl(ST)                                      CsCl(ST2)            Cs3LaCl6(ST)                                                                  CsLa2Cl7(ST)                            Cs3CeCl6(ST)                            CsCe2Cl7(ST)

 

CeCl3-CsCl-LiCl

GSalt-liquid                                 LiCl(ST)                              CsCl(ST)                                      CsCl(ST2)

LiCs2Cl3(ST)                              CeCl3(ST)                                   Cs3CeCl6(ST)                            CsCe2Cl7(ST)

 

CeCl3-CsCl-NaCl

GSalt-liquid                                 NaCl(ST)                            CsCl(ST)                                      CsCl(ST2)

CeCl3(ST)                                   Na3Ce5Cl18(ST)                      Cs3CeCl6(ST)                            CsCe2Cl7(ST)

 

CeCl3-CsCl-RbCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST) 

CeCl3(ST)                                   Rb2CeCl5(ST)                           Rb3CeCl6(ST)                           RbCe2Cl7(ST)                   Cs3CeCl6(ST)                                                                         CsCe2Cl7(ST)

 

CeCl3-KCl-LaCl3

GSalt-liquid                                 RareEarth-Chloride(ss)          KCl(ST)                                         K2LaCl5(ST)                K3La5Cl18(ST)                                                                     K2CeCl5(ST)                              K3CeCl6(ST)                              K3Ce5Cl18(ST)

 

CeCl3-KCl-LiCl

GSalt-liquid                                 KCl(ST)                                         LiCl(ST)                              CeCl3(ST)               K2CeCl5(ST)                                                                       K3CeCl6(ST)                              K3Ce5Cl18(ST)

 

CeCl3-KCl-NaCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CeCl3(ST)            Na3Ce5Cl18(ST)                                                                 K2CeCl5(ST)                              K3CeCl6(ST)                              K3Ce5Cl18(ST)

 

CeCl3-KCl-RbCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CeCl3(ST)                 K2CeCl5(ST)                                                                       K3CeCl6(ST)                              K3Ce5Cl18(ST)                          Rb2CeCl5(ST)            Rb3CeCl6(ST)                                                                           RbCe2Cl7(ST)

 

CeCl3-LaCl3-LiCl

GSalt-liquid                                 RareEarth-Chloride(ss)          LiCl(ST)

 

CeCl3-LaCl3-NaCl

GSalt-liquid                                 RareEarth-Chloride(ss)          NaCl(ST)                                     Na3La5Cl18(ST)             Na3Ce5Cl18(ST)

 

CeCl3-LaCl3-RbCl

GSalt-liquid                                 RareEarth-Chloride(ss)          RbCl(ST)                                     Rb2LaCl5(ST)         Rb3LaCl6(ST)                                                             RbLa2Cl7(ST)                            Rb2CeCl5(ST)                           Rb3CeCl6(ST)              RbCe2Cl7(ST)

 

CeCl3-LiCl-NaCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CeCl3(ST)          Na3Ce5Cl18(ST)

 

CeCl3-LiCl-RbCl

GSalt-liquid                                 LiCl(ST)                                        RbCl(ST)                            LiRbCl2(ST)              CeCl3(ST)                                                                        Rb2CeCl5(ST)                           Rb3CeCl6(ST)                           RbCe2Cl7(ST)

 

CeCl3-NaCl-RbCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CeCl3(ST)        Na3Ce5Cl18(ST)                                                                      Rb2CeCl5(ST)                           Rb3CeCl6(ST)                           RbCe2Cl7(ST)

 

CoCl2-FeCl2-FeCl3

BSalt-liquid                                 MCl2_SOLID                               FeCl3(ST)                                    CoFe2Cl8(ST)

 

CoCl2-FeCl2-KCl

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)          

AAlk2MX4 (J-option)         KCl(ST)         

 

CoCl2-FeCl2-LiCl

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)            

AAlk2MX4 (J-option)            BAlkCl-ss_rocksalt (J-option)                                       Li6FeCl8(ST)              Li4CoCl6(ST)

 

CoCl2-FeCl2-MgCl2

BSalt-liquid                                 MCl2_SOLID   

 

CoCl2-FeCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID    

 

CoCl2-FeCl2-NaCl

BSalt-liquid                                 MCl2_SOLID                               AAlk2MX4(J-option)         NaCl(ST)           

 

CoCl2-FeCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID(I-option)             

 

CoCl2-FeCl3-KCl

BSalt-liquid                                 KCl(ST)                               FeCl3(ST)                                    KFeCl4(ST)             CoCl2(ST)                                                                  KCoCl3(ST)                                 K2CoCl4(ST)                              CoFe2Cl8(ST)

 

CoCl2-FeCl3-LiCl

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                       FeCl3(ST)             LiFeCl4(ST)                                                                      CoCl2(ST)                                   LiCoCl3(ST)                                Li2CoCl4(ST)            Li4CoCl6(ST)                                                            CoFe2Cl8(ST)

 

CoCl2-FeCl3-MgCl2

BSalt-liquid                                 MCl2_SOLID                               FeCl3(ST)                                    MgFe2Cl8(ST)           CoFe2Cl8(ST)

 

CoCl2-FeCl3-MnCl2

BSalt-liquid                                 MCl2_SOLID                               FeCl3(ST)                                    MnFe2Cl8(ST)               CoFe2Cl8(ST)

 

CoCl2-FeCl3-NaCl

BSalt-liquid                                 NaCl(ST)                            FeCl3(ST)                           NaFeCl4(ST)               CoCl2(ST)                                                              Na2CoCl4(ST)                           CoFe2Cl8(ST)     

        

CoCl2-FeCl3-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       FeCl3(ST)                                    CoFe2Cl8(ST)           NiFe2Cl8(ST)

 

CoCl2-KCl-LiCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)              

BAlkCl-ss_rocksalt (J-option)                                       CoCl2(ST)                                   Li4CoCl6(ST)

 

CoCl2-KCl-MgCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)                                        

AAlk2MX4 (J-option)         KCl(ST)                               K3Mg2Cl7(ST)            

 

CoCl2-KCl-MnCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)           

AAlk2MX4 (J-option)          KCl(ST)                               K4MnCl6(ST)                              K3Mn2Cl7(ST)       

 

CoCl2-KCl-NaCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                                   AAlk2MX4 (J-option)        BAlkCl-ss_rocksalt (J-option)        CoCl2(ST)        

 

CoCl2-KCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       AAMX3-Perovskite (J-option)           

AAlk2MX4 (J-option)          KCl(ST)      

 

CoCl2-LiCl-MgCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)      

AAlk2MX4  (J-option)         BAlkCl-ss_rocksalt (J-option)                                       Li4CoCl6(ST)

 

CoCl2-LiCl-MnCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)           

AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)                                       Li4CoCl6(ST)

 

CoCl2-LiCl-NaCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)         BAlkCl-ss_rocksalt (J-option)                                                  CoCl2(ST)                                   Li4CoCl6(ST)        

 

CoCl2-LiCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAMX3-Perovskite (J-option)                       AAlk2MX4 (J-option)                                              BAlkCl-ss_rocksalt (J-option)                                       Li4CoCl6(ST)                          Li6NiCl8(ST)

 

CoCl2-MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID          

 

CoCl2-MgCl2-NaCl

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)  

AAlk2MX4 (J-option)          NaCl(ST)           

 

CoCl2-MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)     

 

CoCl2-MnCl2-NaCl

BSalt-liquid                                 MCl2_SOLID                               AAlk2MX4 (J-option)           NaCl(ST)            Na6MnCl8(ST)                                                                  Na2Mn3Cl8(ST)                        NaMn4Cl9(ST)                           Na9Mn11Cl31(ST)

 

CoCl2-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)  

 

CoCl2-NaCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)         AAlk2MX4 (J-option)                         NaCl(ST)          

 

CsCl-KCl-LaCl3

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST) 

LaCl3(ST)                            K2LaCl5(ST)                               K3La5Cl18(ST)                          Cs3LaCl6(ST)                     CsLa2Cl7(ST)

 

CsCl-KCl-LiCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)                  LiCs2Cl3(ST)

 

CsCl-KCl-MgCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)       

AAlkCl-ss_rocksalt (J-option)                                       MgCl2(ST)                                   K3Mg2Cl7(ST)             CsCl(ST)                                                         CsMg3Cl7(ST)                           Cs3MgCl5(ST)

 

CsCl-KCl-NaCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)

 

CsCl-KCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)

 

CsCl-KCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)        AAlkCl-ss_rocksalt (J-option)        SrCl2(ST)                                   SrCl2(ST2)                       KSr2Cl5(ST)                                             CsCl(ST)     

 

CsCl-LaCl3-LiCl

GSalt-liquid                                 LiCl(ST)                                      CsCl(ST)                                      CsCl(ST2)

LiCs2Cl3(ST)                              LaCl3(ST)                              Cs3LaCl6(ST)                            CsLa2Cl7(ST)

 

CsCl-LaCl3-NaCl

GSalt-liquid                                 NaCl(ST)                            CsCl(ST)                                      CsCl(ST2)                           

LaCl3(ST)                                    Na3La5Cl18(ST)                       Cs3LaCl6(ST)                            CsLa2Cl7(ST)

 

CsCl-LaCl3-RbCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                                   CsCl(ST) 

LaCl3(ST)                           Rb2LaCl5(ST)                            Rb3LaCl6(ST)                            RbLa2Cl7(ST)                Cs3LaCl6(ST)                                                                           CsLa2Cl7(ST)

 

CsCl-LiCl-MgCl2

DSalt-liquid                                 MCl2_SOLID                               BAMX3-Perovskite (J-option)   

BAlk2MX4 (J-option)          AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)                LiCs2Cl3(ST)                                                                    CsMg3Cl7(ST)                           Cs3MgCl5(ST)

 

CsCl-LiCl-NaCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)

LiCs2Cl3(ST)

 

CsCl-LiCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       LiRbCl2(ST)            CsCl(ST)                                          LiCs2Cl3(ST)

 

CsCl-LiCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       LiCl(ST)                               

SrCl2(ST)                                     SrCl2(ST2)                          CsCl(ST)                                      CsCl(ST2)

LiCs2Cl3(ST)

 

CsCl-MgCl2-NaCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)                 

NaCl(ST)                            MgCl2(ST)                                   CsCl(ST)                                      CsCl(ST2)

CsMg3Cl7(ST)                           Cs3MgCl5(ST)     

 

CsCl-MgCl2-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)                 

AAlkCl-ss_rocksalt (J-option)                                                MgCl2(ST)                                   CsCl(ST)

CsMg3Cl7(ST)                           Cs3MgCl5(ST)

 

CsCl-MgCl2-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       (Ca,Sr,[Ba,Mg])Cl2(ss)          

BAlk2MX4 (J-option)        MgCl2(ST)                                   SrCl2(ST2)                                  CsCl(ST)

CsCl(ST2)                                    CsMg3Cl7(ST)                           Cs3MgCl5(ST)

 

CsCl-NaCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       CsCl(ST)

 

CsCl-NaCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       NaCl(ST)

SrCl2(ST)                                     SrCl2(ST2)                                  CsCl(ST)                                      CsCl(ST2)

 

CsCl-RbCl-SrCl2                

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                                    

AAlkCl-ss_rocksalt (J-option)                                                 SrCl2(ST)                                     SrCl2(ST2)         RbSr2Cl5(ST)                                          CsCl(ST)

 

FeCl2-FeCl3-KCl

BSalt-liquid                                 KCl(ST)                               FeCl2(ST)                                    FeCl3(ST)            KFeCl3(ST)                                                                      KFeCl4(ST)                                 K2FeCl4(ST)

 

FeCl2-FeCl3-LiCl

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                       FeCl2(ST)        FeCl3(ST)                                                                    LiFeCl4(ST)                                Li2FeCl4(ST)                              Li6FeCl8(ST)

 

FeCl2-FeCl3-MgCl2

BSalt-liquid                                 MCl2_SOLID                               FeCl3(ST)                                    MgFe2Cl8(ST)

 

FeCl2-FeCl3-MnCl2

BSalt-liquid                                 MCl2_SOLID                               FeCl3(ST)                                    MnFe2Cl8(ST)

 

FeCl2-FeCl3-NaCl

BSalt-liquid                                 NaCl(ST)                            FeCl2(ST)                                    FeCl3(ST)                   NaFeCl4(ST)                                                                      Na2FeCl4(ST)

 

FeCl2-FeCl3-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       FeCl3(ST)                                    NiFe2Cl8(ST)

 

FeCl2-KCl-LiCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)        

BAlkCl-ss_rocksalt (J-option)                                       FeCl2(ST)                            Li6FeCl8(ST)                   

 

FeCl2-KCl-MgCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)        

AAlk2MX4 (J-option)         KCl(ST)                               K3Mg2Cl7(ST)                          

 

FeCl2-KCl-MnCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)        

AAlk2MX4 (J-option)         KCl(ST)                               K4MnCl6(ST)                              K3Mn2Cl7(ST)

 

FeCl2-KCl-NaCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                               AAlk2MX4 (J-option)                     BAlkCl-ss_rocksalt (J-option)                                               FeCl2(ST)                        

 

FeCl2-KCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAMX3-Perovskite (J-option)          

AAlk2MX4 (J-option)            KCl(ST)        

 

FeCl2-LiCl-MgCl2 

BSalt-liquid                                 MCl2_SOLID                               AAlk2MX4 (J-option)          

BAlkCl-ss_rocksalt (J-option)                                                   Li6FeCl8(ST)    

 

FeCl2-LiCl-MnCl2

BSalt-liquid                                 MCl2_SOLID                               AAlk2MX4 (J-option)        

BAlkCl-ss_rocksalt (J-option)                                       Li6FeCl8(ST)

 

FeCl2-LiCl-NaCl

BSalt-liquid                                 AAlk2MX4 (J-option)           BAlkCl-ss_rocksalt (J-option)                        FeCl2(ST)                                                                                   Li6FeCl8(ST)

 

FeCl2-LiCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       AAlk2MX4 (J-option)        

BAlkCl-ss_rocksalt (J-option)                                       Li6FeCl8(ST)                       Li6NiCl8(ST)

 

FeCl2-MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                       

 

FeCl2-MgCl2-NaCl

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)                            AAlk2MX4 (J-option)                                                   NaCl(ST)         

 

FeCl2-MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option) 

 

FeCl2-MnCl2-NaCl

BSalt-liquid                                 MCl2_SOLID                               AAlk2MX4 (J-option)          NaCl(ST)          Na6MnCl8(ST)                                                                           Na2Mn3Cl8(ST)                        NaMn4Cl9(ST)                           Na9Mn11Cl31(ST)             

 

FeCl2-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)         

 

FeCl2-NaCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAlk2MX4 (J-option)          NaCl(ST)         

 

FeCl3-KCl-LiCl

BSalt-liquid                                 KCl(ST)                                         LiCl(ST)                              FeCl3(ST)                LiFeCl4(ST)                                                                       KFeCl4(ST)

 

FeCl3-KCl-MgCl2

BSalt-liquid                                 KCl(ST)                               MgCl2(ST)                                   KMgCl3(ST)

K2MgCl4(ST)                              K3Mg2Cl7(ST)                           FeCl3(ST)                                    MgFe2Cl8(ST)        KFeCl4(ST)

      

FeCl3-KCl-MnCl2

BSalt-liquid                                 KCl(ST)                               MnCl2(ST)                                   KMnCl3(ST) K4MnCl6(ST)                                                                          K3Mn2Cl7(ST)                            FeCl3(ST)                                    KFeCl4(ST)                    MnFe2Cl8(ST)

 

FeCl3-KCl-NaCl

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                                FeCl3(ST)          NaFeCl4(ST)                                                                            KFeCl4(ST)

 

FeCl3-KCl-NiCl2

BSalt-liquid                                 KCl(ST)                                     FeCl3(ST)                                    KFeCl4(ST)                       NiCl2(ST)                                                                            KNiCl3(ST)                                  NiFe2Cl8(ST)

 

FeCl3-LiCl-MgCl2

BSalt-liquid                                 MCl2_SOLID                               BAlkCl-ss_rocksalt (J-option)                

FeCl3(ST)                                    LiFeCl4(ST)                                MgFe2Cl8(ST)

 

FeCl3-LiCl-MnCl2

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                                  MnCl2(ST)              Li2MnCl4(ST)                                                        FeCl3(ST)                                    LiFeCl4(ST)                                MnFe2Cl8(ST)

 

FeCl3-LiCl-NaCl

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                                 FeCl3(ST)                      LiFeCl4(ST)                                                                      NaFeCl4(ST)

 

FeCl3-LiCl-NiCl2

BSalt-liquid                                 BAlkCl-ss_rocksalt (J-option)                                                   FeCl3(ST)                    LiFeCl4(ST)                                                                                 NiCl2(ST)                                     Li2NiCl4(ST)                               Li6NiCl8(ST)                        NiFe2Cl8(ST)

 

FeCl3-MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                               FeCl3(ST)                                    MgFe2Cl8(ST)           MnFe2Cl8(ST)

 

FeCl3-MgCl2-NaCl

BSalt-liquid                                 NaCl(ST)                                    MgCl2(ST)                                   NaMgCl3(ST) Na2MgCl4(ST)                                                        FeCl3(ST)                                    NaFeCl4(ST)                              MgFe2Cl8(ST)

 

FeCl3-MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)         FeCl3(ST)                                    MgFe2Cl8(ST)        NiFe2Cl8(ST)

 

FeCl3-MnCl2-NaCl

BSalt-liquid                                 NaCl(ST)                                     MnCl2(ST)                                   Na2MnCl4(ST) Na6MnCl8(ST)                                                                          Na2Mn3Cl8(ST)                        NaMn4Cl9(ST)                           Na9Mn11Cl31(ST)      FeCl3(ST)                                                                     NaFeCl4(ST)                              MnFe2Cl8(ST)

 

FeCl3-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)                                                 FeCl3(ST)                                                                   MnFe2Cl8(ST)              NiFe2Cl8(ST)

 

FeCl3-NaCl-NiCl2

BSalt-liquid                                 NaCl(ST)                            FeCl3(ST)                                    NaFeCl4(ST)                 NiCl2(ST)                                                                NiFe2Cl8(ST)

 

KCl-LaCl3-LiCl

GSalt-liquid                                 KCl(ST)                                         LiCl(ST)                                        LaCl3(ST)          K2LaCl5(ST)                                                                      K3La5Cl18(ST)

 

KCl-LaCl3-NaCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                                 LaCl3(ST)              Na3La5Cl18(ST)                                                                 K2LaCl5(ST)                               K3La5Cl18(ST)

 

KCl-LaCl3-RbCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                                  LaCl3(ST)                K2LaCl5(ST)                                                                  K3La5Cl18(ST)                          Rb2LaCl5(ST)                            Rb3LaCl6(ST)                     RbLa2Cl7(ST)

 

KCl-LiCl-MgCl2

ASalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)     

AAlk2MX4 (J-option)         AAlkCl-ss_rocksalt (J-option)                                       K3Mg2Cl7(ST)                   LiKMgCl4(ST)                          

 

KCl-LiCl-MnCl2

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)                

BAlkCl-ss_rocksalt (J-option)                                       MnCl2(ST)                                   K4MnCl6(ST)                          K3Mn2Cl7(ST)

 

KCl-LiCl-NaCl

ASalt-liquid                                 AAlkCl-ss_rocksalt (J-option)

 

KCl-LiCl-NiCl2

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                                   AAlk2MX4 (J-option)       

BAlkCl-ss_rocksalt (J-option)                                       NiCl2(ST)                            Li6NiCl8(ST)                        

 

KCl-LiCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       LiRbCl2(ST)

 

KCl-LiCl-SrCl2

DSalt-liquid                                 BAlk2MX4 (J-option)          KCl(ST)                                         LiCl(ST)   

SrCl2(ST)                                     SrCl2(ST2)                             KSr2Cl5(ST)

 

KCl-MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)                

AAlk2MX4 (J-option)          KCl(ST)                               K3Mg2Cl7(ST)                           K4MnCl6(ST)          K3Mn2Cl7(ST)

 

KCl-MgCl2-NaCl

ASalt-liquid                                 AAMX3-Perovskite (J-option)                                       AAlk2MX4 (J-option)            AAlkCl-ss_rocksalt (J-option)                                                              MgCl2(ST)                                 K3Mg2Cl7(ST)                     

 

KCl-MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAMX3-Perovskite (J-option)           

AAlk2MX4 (J-option)           KCl(ST)                               K3Mg2Cl7(ST)

 

KCl-MgCl2-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)   AAlkCl-ss_rocksalt (J-option)                                                              MgCl2(ST)                                   K3Mg2Cl7(ST)

 

KCl-MgCl2-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                                   (Ca,Sr,[Ba,Mg])Cl2(ss)                             BAlk2MX4 (J-option)          KCl(ST)                               MgCl2(ST)                                   K3Mg2Cl7(ST)                 SrCl2(ST2)                                                        KSr2Cl5(ST)

 

KCl-MgCl2-ZnCl2

ISalt-liquid                                   KCl(ST)                                         MgCl2(ST)                                   KMgCl3(ST)

K2MgCl4(ST)                              K3Mg2Cl7(ST)                           ZnCl2(ST)                                    K2ZnCl4(ST)

K5Zn4Cl13(ST)                          KZn2Cl5(ST)

 

KCl-MnCl2-NaCl

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                             AAlk2MX4 (J-option)                             BAlkCl-ss_rocksalt (J-option)                                             MnCl2(ST)                                   Na6MnCl8(ST)                      Na2Mn3Cl8(ST)                        NaMn4Cl9(ST)                           Na9Mn11Cl31(ST)                    K4MnCl6(ST)                     K3Mn2Cl7(ST)                       

 

KCl-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)         AAMX3-Perovskite (J-option)           

KCl(ST)                               K4MnCl6(ST)                              K3Mn2Cl7(ST)

 

KCl-NaCl-NiCl2

BSalt-liquid                                 AAMX3-Perovskite (J-option)                                              

BAlkCl-ss_rocksalt (J-option)                                       NiCl2(ST)     

 

KCl-NaCl-PbCl2

HSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                               PbCl2(ST)   K2PbCl4(ST)                                                                        KPb2Cl5(ST)

 

KCl-NaCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)           

 

KCl-NaCl-SrCl2

DSalt-liquid                                 BAlk2MX4 (J-option)         AAlkCl-ss_rocksalt (J-option)           

SrCl2(ST)                                     SrCl2(ST2)                                  KSr2Cl5(ST)

 

KCl-NaCl-ZnCl2

ISalt-liquid                                   AAlkCl-ss_rocksalt (J-option)                                               ZnCl2(ST)   Na2ZnCl4(ST)                                                        K2ZnCl4(ST)                               K5Zn4Cl13(ST)                          KZn2Cl5(ST)                                

KCl-RbCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                                AlkM2Cl5 (I-option)                BAlk2MX4 (J-option)         AAlkCl-ss_rocksalt (J-option)                                                  SrCl2(ST)                   SrCl2(ST2)          

 

LaCl3-LiCl-NaCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       LaCl3(ST)                         Na3La5Cl18(ST)

 

LaCl3-LiCl-RbCl

GSalt-liquid                                 LiCl(ST)                                        RbCl(ST)                            LiRbCl2(ST)            LaCl3(ST)                                                                     Rb2LaCl5(ST)                            Rb3LaCl6(ST)                            RbLa2Cl7(ST)

 

LaCl3-NaCl-RbCl

GSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       LaCl3(ST)                  Na3La5Cl18(ST)                                                                      Rb2LaCl5(ST)                            Rb3LaCl6(ST)                            RbLa2Cl7(ST)

 

LiCl-MgCl2-MnCl2

BSalt-liquid                                 MCl2_SOLID                               AAlk2MX4(J-option)           

BAlkCl-ss_rocksalt (J-option)                   

 

LiCl-MgCl2-NaCl

ASalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)                 

AAlk2MX4 (J-option)         AAlkCl-ss_rocksalt (J-option)    

 

LiCl-MgCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAlk2MX4(J-option)            

BAlkCl-ss_rocksalt (J-option)                                       Li6NiCl8(ST)

 

LiCl-MgCl2-RbCl

DSalt-liquid                                 MCl2_SOLID                               BAMX3-Perovskite (J-option)             

BAlk2MX4 (J-option)          AAlkCl-ss_rocksalt (J-option)                                       LiRbCl2(ST)          

 

LiCl-MgCl2-SrCl2

DSalt-liquid                                 MCl2_SOLID                               (Ca,Sr,[Ba,Mg])Cl2(ss)                               

AAlkCl-ss_rocksalt (J-option)                                       SrCl2(ST2)

 

LiCl-MnCl2-NaCl

BSalt-liquid                                 AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)               

MnCl2(ST)                                   Na6MnCl8(ST)                           Na2Mn3Cl8(ST)                        NaMn4Cl9(ST)             Na9Mn11Cl31(ST)

 

LiCl-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)       AAlk2MX4 (J-option)         

BAlkCl-ss_rocksalt (J-option)                                       Li6NiCl8(ST)     

 

LiCl-NaCl-NiCl2

BSalt-liquid                                 AAlk2MX4 (J-option)          BAlkCl-ss_rocksalt (J-option)                 

NiCl2(ST)                                     Li6NiCl8(ST)

 

LiCl-NaCl-RbCl

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       LiRbCl2(ST)

 

LiCl-NaCl-SrCl2

DSalt-liquid                                 AAlkCl-ss_rocksalt (J-option)                                       SrCl2(ST)                   SrCl2(ST2)        

 

LiCl-RbCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                                 LiCl(ST)   

RbCl(ST)                                     LiRbCl2(ST)                                SrCl2(ST)                                     SrCl2(ST2)            RbSr2Cl5(ST)

 

MgCl2-MnCl2-NaCl

BSalt-liquid                                 MCl2_SOLID                               AAMX3-Perovskite (J-option)                 

AAlk2MX4 (J-option)         NaCl(ST)                            Na6MnCl8(ST)                           Na2Mn3Cl8(ST)                  NaMn4Cl9(ST)                                                                      Na9Mn11Cl31(ST)

 

MgCl2-MnCl2-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)          

 

MgCl2-NaCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAMX3-Perovskite (J-option)                     AAlk2MX4 (J-option)                                               NaCl(ST)

 

MgCl2-NaCl-RbCl

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                       BAlk2MX4 (J-option)    

AAlkCl-ss_rocksalt (J-option)                                       MgCl2(ST)                 

 

MgCl2-NaCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                           (Ca,Sr,[Ba,Mg])Cl2(ss)                     BAlk2MX4 (J-option)          NaCl(ST)                            MgCl2(ST)                                   SrCl2(ST2)

 

MgCl2-NaCl-ZnCl2

ISalt-liquid                                   NaCl(ST)                            MgCl2(ST)                                   NaMgCl3(ST)

Na2MgCl4(ST)                          ZnCl2(ST)                                    Na2ZnCl4(ST)

 

MgCl2-RbCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                           (Ca,Sr,[Ba,Mg])Cl2(ss)                     BAlk2MX4 (J-option)          RbCl(ST)                            MgCl2(ST)                                   SrCl2(ST2)

RbSr2Cl5(ST)

 

MnCl2-NaCl-NiCl2

BSalt-liquid                                 MCl2_SOLID (I-option)      AAlk2MX4 (J-option)         NaCl(ST)

Na6MnCl8(ST)                           Na2Mn3Cl8(ST)                        NaMn4Cl9(ST)                           Na9Mn11Cl31(ST)

 

NaCl-RbCl-SrCl2

DSalt-liquid                                 BAMX3-Perovskite (J-option)                                              

AAlkCl-ss_rocksalt (J-option)                                               SrCl2(ST)                                     SrCl2(ST2)                          RbSr2Cl5(ST)

 

 

Anion = F

 

CaF2-KF-LiF

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                                   LiF(ST)            

KF(ST)                                          CaF2(ST)                                     CaF2(ST2)

 

CaF2-KF-MgF2

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                       CAlk2MX4 (J-option)                   MgF2(ST)                                    KF(ST)                                          CaF2(ST)                                     CaF2(ST2)

 

CaF2-KF-NaF

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                                    AlkF(ssA) (J-option)         CaF2(ST)                                                                CaF2(ST2)

 

CaF2-LiF-MgF2

ASalt-liquid                                 MgF2-[LiF](ss)                           LiF-[MgF2](ss)                           CaF2(ST)

CaF2(ST2)

 

CaF2-LiF-NaF

ASalt-liquid                                 NaF-[LiF](ss)                              LiF(ST)                                         CaF2(ST)           CaF2(ST2)

 

CaF2-MgF2-NaF

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                                    NaF(ST)              MgF2(ST)       CaF2(ST)                                                                     CaF2(ST2)              

 

CsF-KF-LiF

ESalt-liquid                                 AlkF(ssA) (J-option)          AlkF(ssB) (J-option)          LiF(ST)                    LiCsF2(ST)

 

CsF-KF-NaF

ESalt-liquid                                 AlkF(ssA) (J-option)          AlkF(ssB) (J-option)         

 

CsF-KF-RbF

ESalt-liquid                                 AlkF(ssA) (J-option)                                                    AlkF(ssB) (J-option)         

 

CsF-LiF-NaF

ESalt-liquid                                 NaF-[LiF](ss)                              AlkF(ssA) (J-option)          LiF(ST)             LiCsF2(ST)

 

CsF-LiF-RbF

ESalt-liquid                                 AlkF(ssA) (J-option)             LiF(ST)                                   LiRbF2(ST)              LiCsF2(ST)

 

CsF-NaF-RbF

ESalt-liquid                                 AlkF(ssA) (J-option)           

 

KF-LiF-MgF2

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                                MgF2-[LiF](ss)                    LiF-[MgF2](ss)                                                                           CAlk2MX4 (J-option)          KF(ST)

 

KF-LiF-NaF       

ASalt-liquid                                 NaF-[LiF](ss)                              AlkF(ssA) (J-option)          LiF(ST)

 

KF-LiF-RbF

ESalt-liquid                                 AlkF(ssA) (J-option)                                                                   LiF(ST)                                    LiRbF2(ST)

 

KF-MgF2-NaF

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                       CAlk2MX4 (J-option)              

AlkF(ssA) (J-option)                                                                  MgF2(ST)                  

 

KF-NaF-RbF

ESalt-liquid                         AlkF(ssA) (J-option)                 

 

LiF-MgF2-NaF

ASalt-liquid                                 CAMX3-Perovskite (J-option)                                              NaF-[LiF](ss)            MgF2-[LiF](ss)                                                                    LiF-[MgF2](ss)                            

 

LiF-NaF-RbF

ESalt-liquid                                 NaF-[LiF](ss)                              AlkF(ssA) (J-option)                         LiF(ST)              LiRbF2(ST)

 

LiF-PuF3-PuF4

JSalt-liquid                                  LiF(ST)                                         PuF3(ST)                            PuF4(ST)  

Li3PuF7(ST)                               Li4PuF8(ST)                               LiPu2F9(ST)                               LiPu4F17(ST)

Li7Pu6F31(ST)          

 

LiF-PuF3-ThF4

JSalt-liquid                                  (Th,U,Pu)F4(ss)                         Li(Th,U,Pu)4F17(ss)(I-option)  

Li(Th,U,Pu)2F9(ss)(I-option)                                         Li7(Th,U,Pu)6F31(ss)(I-option)

Li3(Th,U,Pu)F7(ss)(I-option)                                                       LiF(ST)

ThF4(ST)                                     PuF3(ST)                                     PuF4(ST)                                     Li4PuF8(ST)

 

LiF-PuF3-UF3

JSalt-liquid                                  (U,Pu)F3(ss)                               (Th,U,Pu)F4(ss)

Li(Th,U,Pu)4F17(ss)(I-option)                                       Li(Th,U,Pu)2F9(ss)(I-option)

Li7(Th,U,Pu)6F31(ss)(I-option)                                      Li3(Th,U,Pu)F7(ss)(I-option)

Li4(U,Pu)F8(ss)(I-option)    LiF(ST)                                         UF3(ST)                                       UF4(ST)

PuF3(ST)                                     PuF4(ST)

 

LiF-PuF4-UF3

JSalt-liquid                                  (U,Pu)F3(ss)                               (Th,U,Pu)F4(ss)

Li(Th,U,Pu)4F17(ss)(I-option)                                       Li(Th,U,Pu)2F9(ss)(I-option)

Li7(Th,U,Pu)6F31(ss)(I-option)                                      Li3(Th,U,Pu)F7(ss)(I-option)

Li4(U,Pu)F8(ss)(I-option)    LiF(ST)                                         UF3(ST)                                       UF4(ST)

PuF3(ST)                                     PuF4(ST)

 

LiF-PuF4-UF4

JSalt-liquid                                  (U,Pu)F3(ss)                               (Th,U,Pu)F4(ss)

Li(Th,U,Pu)4F17(ss)(I-option)                                       Li(Th,U,Pu)2F9(ss)(I-option)

Li7(Th,U,Pu)6F31(ss)(I-option)                                      Li3(Th,U,Pu)F7(ss)(I-option)

Li4(U,Pu)F8(ss)(I-option)    LiF(ST)                                         UF3(ST)                                       UF4(ST)

PuF3(ST)                                     PuF4(ST)

 

LiF-ThF4-UF4

JSalt-liquid                                  (Th,U,Pu)F4(ss)                         Li(Th,U,Pu)4F17(ss)(I-option)

Li(Th,U,Pu)2F9(ss)(I-option)                                         Li7(Th,U,Pu)6F31(ss)(I-option)

Li3(Th,U,Pu)F7(ss)(I-option)                                         LiF(ST)                                        ThF4(ST)

UF3(ST)                                       UF4(ST)                                       Li4UF8(ST)

 

LiF-UF3-UF4

JSalt-liquid                                  LiF(ST)                                         UF3(ST)                                       UF4(ST)

Li3UF7(ST)                                 Li4UF8(ST)                                 LiU2F9(ST)                                 LiU4F17(ST)

Li7U6F31(ST)

 

 

TABLE 4 : List of phases for some RECIPROCAL TERNARY systems :

 

Only the MAIN reciprocal ternary systems are presented below. These are systems for which the two anions are Cl and F and the cations are two of Li, Na, K, Mg and Ca. 

 

Reciprocal ternary phase diagrams (those containing two cations and two anions) may be calculated using the phases listed below for each system. The following code of colours is used:

- For all reciprocal ternary systems in purple, complete assessments based on all experimental data from the literature are available. Reciprocal ternary parameters were added for the liquid and/or other phases (solid solutions) if needed.

- For all reciprocal ternary systems in blue, no experimental data could be found in the literature. Consequently, the thermodynamic properties of the liquid (and solid solutions if they exist) are simply estimated from the optimized parameters of the 4 binary common ion subsystems using proper interpolation methods.

 

Beware - if some ternary or quaternary phases are unknown, incorrect phase equilibria may be calculated. 

 

Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.

 

(J-option) ― the phase may display a 3-phase immiscibility; selection with the J-option is required.

 

 

Ca, K // Cl, F

ASalt-liquid (J-option)        CAMX3-Perovskite (J-option)                                                    KCl(ST)     

KF(ST)                                          CaF2(ST)                                     CaF2(ST2)                                  CaCl2(ST)          CaFCl(ST)

 

Ca, Li // Cl, F

ASalt-liquid (J-option)                                                                LiCl(ST)                              LiF(ST)                                           CaF2(ST)            CaF2(ST2)                                  CaCl2(ST)                                   CaFCl(ST)

 

Ca, Mg // Cl, F

ASalt-liquid (J-option)         (Ca,Sr,[Ba,Mg])Cl2(ss)            MgF2(ST)                                    MgCl2(ST)        CaF2(ST)         CaF2(ST2)                                                                          CaFCl(ST)

 

Ca, Na // Cl, F

ASalt-liquid (J-option)          AAlkCl-ss_rocksalt (J-option)                                       NaF(ST)           CaF2(ST)                                                                  CaF2(ST2)                                  CaCl2(ST)                                   CaFCl(ST)

 

K, Li // Cl, F

ASalt-liquid (J-option)         KCl(ST)                                         LiCl(ST)                              KF(ST)              LiF(ST)

 

K, Mg // Cl, F

ASalt-liquid (J-option)       CAMX3-Perovskite (J-option)                                                   CAlk2MX4 (J-option)

KCl(ST)                               MgF2(ST)                                    MgCl2(ST)                                   KF(ST)              K3Mg2Cl7(ST)

 

K, Na // Cl, F

ASalt-liquid (J-option)                                                  AlkF(ssA) (J-option)             AAlkCl-ss_rocksalt (J-option)      

 

Li, Mg // Cl, F

ASalt-liquid (J-option)          MCl2_SOLID                               MgF2-[LiF](ss)                           LiF-[MgF2](ss)       

AAlkCl-ss_rocksalt (J-option)            

  

Li, Na // Cl, F

ASalt-liquid (J-option)          NaF-[LiF](ss)                              AAlkCl-ss_rocksalt (J-option)          

LiF(ST)                

 

Mg, Na // Cl, F

ASalt-liquid (J-option)          CAMX3-Perovskite (J-option)                                                    CAlk2MX4 (J-option)     NaCl(ST)                                                             NaF(ST)                                       MgF2(ST)                                    MgCl2(ST)