- one-metal
Eh vs pH Pourbaix diagram
Instructions:
Select a metal, set the molality m of the aqueous species, and specify
the limits of the axes (make sure min < max). The step defines
the position of the labels on the axes. The default system is Cu-H2O
at m = 10-6 and 298.15 K. Click on Calculate to generate
the diagram.
EpH-Web
generates one-metal isothermal Eh vs. pH (Pourbaix) diagram for
various concentrations (m) of solutes in a dilute aqueous phase.
Data are taken from the FACT compound (i.e. pure substances) database.
Here
you are limited to one metallic element and a fixed temperature
(298.15 K). In the EpH
module of the full
package,
your may enter up to 3 metallic elements (to produce a multi-metallic
system) and any temperature. Species may be dropped from the calculation,
and the activity or partial pressure of any phase may be set to
a value other than unity. In addition to the calculated Pourbaix
diagram it is possible to list a table of invariant points, and
perform a detailed chemical equilibrium calculation at any coordinate
on the diagram. Additional constant chemical potentials may also
be specified.
|