LIST OF SOLUTIONS AND COMPOUNDS IN FThall

(1) LIST OF SOLUTIONS

FThall-Bath

Bath NaF-AlF3-CaF2-LiF-MgF2-Al2O3 + dissolved metal (?)

(uncertainties above 1100oC or CR>5 or CR<1.5; ? = metal dissolution)

FThall-CryL

Na-Cryolite-L Na3AlF6-Li3AlF6-[Ca(1.5)AlF6]

Low-temperature solid cryolite Na3AlF6 diss. Ca[2+] & Li[+]

FThall-CryH

Na-Cryolite-H Na3AlF6-Li3AlF6-AlF3-CaF2

High temperature non-stoichiometric cryolite

FThall-LiCB

Li-Cryolite-B Beta-Li3AlF6 dissolving Na[+]

FThall-LiCG

Li-Cryolite-G Gamma-Li3AlF6 dissolving Na[+]

FThall-LiCD

Li-Cryolite-D Delta-Li3AlF6 dissolving Na[+]

FThall-CrLt

Cryolithionite (non-stoichiometric cubic Na3Li3Al2F12 diss. excess Li3AlF6)

use I-option

FThall-NaF

NaF-ss dissolving LiF (Rocksalt)

use I option

FThall-LiF

LiF-ss dissolving MgF2

FThall-MgF2

MgF2-ss dissolving LiF

FThall-Liq

Liquid-Alloy  Liquid light-metal Al,Mg,Ca,Na

Use I Option (Inf. dil. act. coeff. of Ca in Al is estimated)

FThall-FCC

FCC Al-[Na,Mg] solid solution

FThall-HCP

HCP Mg dissolving Al

FThall-BCC

BCC Ca,Na

Use I-option

FThall-AlMg

Gamma Al12Mg17 gamma solid solution

Al-Mg defect solid solution - Laves Phase

FThall-Spin

Spinel MgAl2O4 with dissolved Al2O3

Recommend Option-I

FThall-Mono

Monoxide Rocksalt MgO-CaO-[Al2O3]

use I option

(2) LIST OF COMPOUNDS        (42 compounds)

Li                             S    L   

Li2O                           S    L   

Li2O2                          S   

LiF                            S    L   

Na                             S    L   

NaO2                           S   

Na2O                           S1   S2   S3   L   

Na2O2                          S1   S2  

NaF                            S    L    G   

(NaF)2                         G   

Mg                             S    L    

MgO                            S    L   

MgF2                           S    L   

NaMgF3                         S   

Al                             S    L   

Al2O3                          S1   S2   S3   S4   L   

LiAlO2                         S    

AlF3                           S1   S2   L   

Li3AlF6                        S1   S2   S3  

NaAlO2                         S1   S2  

NaAl9O14                       S   

Na2Al12O19                     S   

Na3AlF6                        S1   S2  

Na5Al3F14                      S   

Na2LiAlF6                      S1   S2  

Al8Mg5                         S   

Al29Mg21                       S   

MgAl2O4                        S   

Na2MgAlF7                      S   

Ca                             S1   S2   L   

CaO                            S    L   

CaO2                           S   

CaF2                           S1   S2   L   

CaAl2O4                        S   

CaAl4O7                        S   

CaAl12O19                      S   

Ca3Al2O6                       S   

CaAlF5                         S1   S2  

Ca2AlF7                        S   

LiCaAlF6                       S   

NaCaAlF6                       S1   S2   S3  

NaCaAl2F9                      S

Note: all gaseous species (NaAlF₄, Na₂AlF₅, AlF₃, AlF, AlOF, etc..) are found in the FACT53 Compound Database.

Note: the FThall database is compatible with C_(graphite), CO_(g), CO_2(g) and other C-O species in the FACT53 Compound Database.